A green and cost-effective biosynthetic approach for the preparation of icosahedral gold nanoparticles (AuNPs) using an aqueous leaf extract of Polygonum minus as reducing and stabilising factor is described. The reduction of Au 3C ions to elemental Au rapidly occurred and is completed within 20 minutes at room temperature. The size of the nanoparticles is highly sensitive to the AuCl 4 ¡ /leaf extract concentration ratio and pH. Transmission electron microscopy and X-ray diffraction data indicated that the nanoparticles were in a crystalline shape (face-centred cubic), mostly icosahedral and nearly monodispersed with an average size of 23 nm. Cyclic voltammetric studies suggested that flavonoids, such as quercetin and myricetin present in the leaf extract had a tendency to donate electrons to Au 3C ions and the formation of elemental Au was possible due to the transfer of electrons from these flavonoids to Au 3C ions. Infrared absorption of the AuNPs and the leaf extract revealed that the oxidised (quinone) form of quercetin and myricetin were presumably the main stabilising agents in the formation of stable nanoparticles. The present biosynthesis of AuNPs was simple, rapid, cost-effective and environmentally friendly. The newly prepared biostabilised icosahedral AuNPs show good catalytic activity in the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP).

No abstract

Organic soil causes major problems in infrastructure development. It has high compressibility and low shear strength, and requires chemical stabilization if it is to be a sustainable geomaterial. This research investigated the strength and microstructural properties of organic soil stabilized with magnesium chloride (MgCl 2 ). Unconfined compressive strength tests were undertaken to assess shear strength properties, and microstructural changes were monitored via field-emission scanning electron microscopy (FESEM) and energy-dispersive X-ray spectrometry (EDAX). The results confirm that MgCl 2 improves the compressive strength of organic soil. The strength of MgCl 2 -stabilized organic soil is increased to around 3 – 5 times that of untreated soil during the first 7 days of curing. FESEM results show that the porosity of organic soil is filled by a new cementitious compound, identified as magnesium silicate hydrate (M-S-H).

Gold nanoparticles (AuNPs) has been recognized as an active and effective catalyst for many organic transformations. Currently, there is a growing need to develop AuNPs synthesis process that avoids the use of toxic chemicals or high energy requirement. In this research, the aqueous Phaleria macrocarpa (Mahkota dewa) dried fruit extract was used in the biosynthesis of AuNPs immobilized on peanut shell powder. The peanut shell supported AuNPs was characterized by UV–visible spectroscopy (UV–Vis), X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA), Nitrogen (N2) adsorption-desorption and atomic absorption spectroscopy (AAS) techniques. The biosynthesized AuNPs was characterized by the appearance of a surface plasmon resonance (SPR) band at 534 nm in the UV–Vis spectrum. The XRD, TEM and TGA analytical data of AuNPs/Peanut shell composite indicated that the AuNPs with face-centred cubic (fcc) crystalline shape, mostly spherical and average particle size of 20.00 ± 4.19 nm were well dispersed on the peanut shell powder support. The FTIR analysis suggested that the C=O and O-H groups in the peanut shell powder have strong affinity to bind and stabilize the AuNPs. The BET surface area of the AuNPs/Peanut shell composite catalyst determined is 35.39 m² g-1 while the BJH pore volume is 0.035 cm3 g-1 with pore diameter of 2.07 nm. AAS elemental analytical data showed the Au loading is 0.03 mmol per gram of catalyst. The catalytic performance of the AuNPs/Peanut shell composite was investigated for the reduction of aqueous methyl blue (MB) at room temperature. The reduction of MB obeyed a pseudo-first-order reaction with the highest rate constant of 0.124 min-1. The supported AuNPs/Peanut shell composite catalyst could be easily recovered and reused for at least three times without significant loss of activity

No abstract