In this paper we are reporting the accelerated sonophotocatalytic degradation of Reactive Red (RR) 198 dye under visible light using dye sensitized TiO(2) activated by ultrasound. The effect of sonolysis, photocatalysis and sonophotocatalysis under visible light has been examined to study the influence on the degradation rates by varying the initial substrate concentration, pH and catalyst loading to ascertain the synergistic effect on the degradation techniques. Ultrasonic activation at 47kHz contributes through cavitation leading to the splitting of H(2)O(2) produced by both photocatalysis and sonolysis. This results in the formation of oxidative species, such as singlet oxygen ((1)O(2)) and superoxide (O2-*) radicals in the presence of oxygen. Sonication increases the amount of reactive radical species, inducing faster oxidation of the substrate and degradation of intermediates and also the deaggregation of the photocatalyst which are responsible for the observed synergy. Further, the photocatalytic activity of RR 198 dye sensitized TiO(2) is demonstrated by the degradation of phenol under visible light and ultrasound. A comparative study using TiO(2), Hombikat UV 100 and ZnO was also carried out.
Investigations were carried out to see the impact of drying air temperature (65, 75 and 85°C) and milk as foaming agent in different concentration levels (0%, 10%, 15%, 20% and 25%) on the chemical properties of foam-mat dried mango juice powder. Chemical properties such as total sugars, ascorbic acid, total carotenes, minerals, total acid, pH, total soluble solids (TSS) and microbial load (fungal and bacterial) of foam-mat dried mango powder were determined. Data were analysed as per two-way anova, Duncan's multiple range test and l.s.d. of AgRes Software statistical package. Almost all chemical properties show decreasing trend with increase in drying air temperature. Microbial load was not detected in foam-mat dried mango powder. It was found that addition of 10% milk as foaming agent and drying at 65°C temperature gave better results.
We report the results of density functional theory (DFT) based calculations on monolayer and bilayer green phosphorene and their heterostructures with MoSe2. Both monolayer and bilayer green phosphorene are direct band gap semiconductors and possess anisotropic carrier mobility as high as 10 4 cm 2 V -1 s -1 . In bilayers, pressure of about 9 GPa induces the semiconductor-metal transition. Moreover, the band gap depends strongly on the thickness of the films and the external electric field. By employing strain-engineering under suitable solution conditions, monolayer and AC-stacked bilayer green phosphorene offer the band edge alignments which can be used for water splitting. The upper limit of the power conversion efficiencies for monolayer, AB-and AC-stacked bilayer green phosphorene heterostructures with MoSe2 is calculated to be 18-21 %. Our results show the possibility of green phosphorene to be used as photocatalytic and photovoltaic material in the energy-related applications.
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