Articles you may be interested inPoly͑chlorotrifluoroethylene͒ ͑PCTFE͒ and other fluoropolymers are increasingly used as inner layer dielectrics. However, these polymers have low surface energies and correspondingly poor adhesive properties. Results are presented on the use of a low-pressure ammonia plasma to enhance the surface bondability of PCTFE. The plasma modified PCTFE film surfaces were characterized by x-ray photoelectron spectroscopy and contact angle measurements. Surface modified films exhibited improved adhesion to electroless copper deposits ͑180°peel test͒ compared to coated PCTFE controls and that underwent no plasma exposure. Annealing studies were conducted between 30 and 100°C to examine the stability of the plasma-modified surfaces. For samples annealed below T g , contact angle measurements indicated that the plasma-introduced groups remained bound on the surface for four weeks. For specimens annealed above T g , the surface functionalities were absorbed within the bulk and surface rearrangement occurred within 10 h of annealing time. As a result of rearrangement, the benefit of adhesion enhancement by plasma is lost and the adhesion to copper is reduced.

Chemical Enhanced Oil Recovery operations involve injecting polymer and surfactants for enhanced recovery. Some of the polymer and surfactant are produced in the form of emulsions. The emulsions need to be treated to recover the oil and reuse water for mixing new polymer for injection. New treatment methods are required to effectively break these emulsions. While chemical treatment and other methods are effective in breaking emulsions formed by electric submersible pumps (ESP's), these methods are not successful in breaking emulsions formed by injected chemicals for CEOR. Reuse of produced water is important in off-shore as well as some on-shore fields. Produced water re-injection requires mixing of fresh polymer with fluid containing produced polymer and traces of oil, which can cause potential incompatibility. Ideally, removal of all produced polymer using a viscosity reducer followed by injection of fresh polymer will improve facility reliability and uptime. Sodium hypochlorite (NaOCl or bleach) was evaluated as a viscosity reducer (VR). Bleach can reduce the viscosity of any HPAM by breaking down the polymer. Polymer destruction fortuitously causes a breakdown of emulsions which releases oil from water and results in improved water quality. After destruction of HPAM, excess bleach was neutralized by chemical means using a neutralizer. After neutralization, the resulting water is free of excess bleach and can be reused for mixing fresh polymer for injection without the risk of degradation of newly mixed polymer. Activating the VR (acidic VR) by pH adjustment can enhance the performance of VR dramatically. Improved oil separation as well as polymer removal can be realized using this technique.