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Methyl-branched volatiles in apples and processed apples are investigated. The ratio of 3-methyl-branched and 2-methyl-branched flavor compounds was determined and the enantiomeric distribution of the latter investigated. The enantiomeric ratios of 2-methyl-branched volatiles are analyzed, using heptakis(2,3-di-O-methyl-6-O-tert-butyldimethylsilyl)-β-cyclodextrin as an efficient enantioselective stationary phase in capillary GC. 2-Methylbutanoic acid and the corresponding esters (methyl−n-hexyl ester), 2-methylbutanol, and 2-methylbutyl acetate were detected as genuine flavor compounds favoring (S)-configuration and high enantiomeric purity (>99%). 3-Methylbutanoic acid, 3-methylbutanol, and 3-methylbutyl acetate are proved to be not genuine compounds of the apple aroma but fermentation products. Keywords: Apple flavor; methyl-branched volatiles; enantioselective capillary gas chromatography; enantioselective multidimensional gas chromatography (enantio-MDGC)

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