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Interface trap passivation at the SiO2∕carbon-terminated (0001¯) face of 4H-SiC utilizing nitridation and hydrogenation has been evaluated. The SiO2∕SiC interface, created by dry thermal oxidation on the C face, shows appreciably higher interface state density near the conduction band compared to the (0001) Si face. A postoxidation anneal in nitric oxide followed by a postmetallization anneal in hydrogen results in dramatic reduction of the trap density by over an order of magnitude near the conduction band. The electrical measurements have been correlated with the interfacial chemistry.

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Nitric oxide postoxidation anneal results in a significant decrease of defect state density (Dit) near the conduction bandedge of n-4H–SiC at the oxide/(112̄0) 4H–SiC interface. Comparison with measurements on the conventional (0001) Si-terminated face shows a similar interface state density following passivation. Medium energy ion scattering provides a quantitative measure of nitrogen incorporation at the SiO2/SiC interface.

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