The equilibrium of N204 with N02 has been determined in cyclohexane, carbon tetrachloride, and acetonitrile The equilibrium constants and enthalpies for N204 dissociation at 298°K have been determined and are respectively, 1.77 X 10-4 and 14.6 kcal in cyclohexane and carbon tetrachloride and 0.30 X 10-4 and 16 kca in acetonitrile. These data are compared with the gas-phase values of 1.51 X 10-1 and 13.64 kcal for N20 dissociation. The differences in gas and solution thermodynamics are discussed.

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