The non-cooperative eutectoid transformation relies on the presence of pre-existing cementite particles in the parent austenitic phase and yields a product, popularly known as the divorced eutectoid. In isothermal conditions, two of the important parameters, which influence the transformation mechanism and determine the final morphology are undercooling (below A 1 temperature) and interparticle spacing. Although, the criteria which governs the morphological transition from lamellar to divorced is experimentally well established, numerical studies that give a detailed exposition of the non-cooperative transformation mechanism, have not been reported extensively. In the present work, we employ a multiphase-field model, that uses the thermodynamic information from the CALPHAD database, to numerically simulate the pulling-away of the advancing ferrite-austenite interface from cementite, which results in a transition from lamellar to divorced eutectoid morphology in Fe-C alloy. We also identify the onset of a concurrent growth and coarsening regime at small inter-particle spacing and low undercooling. We analyze the simulation results to unravel the essential physics behind this complex spacial and temporal evolution pathway and amend the existing criteria by constructing a Lamellar-Divorced-Coarsening (LDC) map.
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