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The formation of carbon structures as a result of decomposition of some organic molecules on the surface of metal fluorides (without molecular decay in a gas) exposed to IR femtosecond laser radiation with a wavelength of 3.3-5.4 µm is revealed. The determining influence of the laser pulse intensity on the efficiency of the decomposition process has been ascertained. A possible mechanism of the decomposition of molecules on the surface and of the growth of carbon structures has been proposed.

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