The paper describes preparation features of functional composites based on ferrites, such as “Ba(Fe1−xGax)12O19/epoxy,” and the results of studying their systems; namely, the correlation between structure, magnetic properties and electromagnetic absorption characteristics. We demonstrated the strong mutual influence of the chemical compositions of magnetic fillers (Ba(Fe1−xGax)12O19 0.01 < x < 0.1 solid solutions), and the main magnetic (coercivity, magnetization, anisotropy field and the first anisotropy constant) and microwave (resonant frequency and amplitude) characteristics of functional composites with 30 wt.% of hexaferrite. The paper presents a correlation between the chemical compositions of composites and amplitude–frequency characteristics. Increase of Ga-content from x = 0 to 0.1 in Ba(Fe1−xGax)12O19/epoxy composites leads to increase of the resonant frequency from 51 to 54 GHz and absorption amplitude from −1.5 to −10.5 dB/mm. The ability to control the electromagnetic properties in these types of composites opens great prospects for their practical applications due to high absorption efficiency, and lower cost in comparison with pure ceramics oxides.
Microwave electromagnetic radiation that ranges from one meter to one millimetre wavelengths is finding numerous applications for wireless communication, navigation and detection, which makes materials able to tune microwave radiation getting widespread interest. Here we offer a new way to tune GHz frequency radiation by using spin-crossover complexes that are known to change their various physical properties under the influence of diverse external stimuli. As a result of electronic re-configuration process, microwave absorption properties differ for high spin and low spin forms of the complex. The evolution of a microwave absorption spectrum for the switchable compound within the region of thermal transition indicates that the high-spin and the low-spin forms are characterized by a different attenuation of electromagnetic waves. Absorption and reflection coefficients were found to be higher in the high-spin state comparing to the low-spin state. These results reveal a considerable potential for the implementation of spin-crossover materials into different elements of microwave signal switching and wireless communication.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.