Abstract:The quest for multifunctional carbon fiber reinforced composites (CFRPs) expedited the use of several nano reinforcements such as zinc oxide nanorods (ZnO) and carbon nanotubes (CNTs). Zinc oxide is a semi-conductor with good piezoelectric and pyroelectric properties. These properties could be transmitted to CFRPs when a nanophase of ZnO is embedded within CFRPs. In lieu of ZnO nanorods, Bucky paper comprising mat of CNTs could be sandwiched in-between composite laminae to construct a functionally graded composite with enhanced electrical conductivities. In this study, different configurations of hybrid composites based on carbon fibers with different combinations of ZnO nanorods and Bucky paper were fabricated. The composites were tested mechanically via tensile and dynamic mechanical analysis (DMA) tests to examine the effect of the different nanoadditives on the stiffness, strength and the damping performance of the hybrid composites. Electrical resistivities of the hybrid composites were probed to examine the contributions of the different nanoadditives. The results suggest that there are certain hybrid composite combinations that could lead to the development of highly multifunctional composites with better strength, stiffness, damping and electrical conductivity.

Phase-change materials (PCMs) are a useful alternative to more traditional methods of thermal management of various applications. PCMs are materials that absorb large amounts of latent heat and undergo solid-to-liquid phase change at near-constant temperature. The goal of the research is to experimentally investigate the thermal properties of a novel shape-stabilized PCM/HDPE composite extruded filament. The extruded filament can then be used in a 3D printer for custom PCM/HDPE shapes. The PCM used in the study is PureTemp PCM 42, which is an organic-based material that melts around 42 °C. Four PCM/HDPE mixtures were investigated (all percentages by mass): 20/80, 30/70, 40/60, and 50/50. Preliminary findings include differential scanning calorimeter (DSC) measurements of melting temperature and latent heat as well as scanning electron microscope (SEM) pictures of filament composition.

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Adding single walled carbon nanotubes (SWCNT) to a polymer matrix can improve the delamination properties of the composite. Due to the complexity of polymer molecules and the curing process, few 3-D Molecular Dynamics (MD) simulations of a polymer-SWCNT composite have been run. Our model runs on the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS), with a COMPASS (Condensed phase Optimized Molecular Potential for Atomistic Simulations Studies) potential. This potential includes non-bonded interactions, as well as bonds, angles and dihedrals to create a MD model for a SWCNT and EPON 862/DETDA (Diethyltoluenediamine) polymer matrix. Two simulations were performed in order to test the implementation of the COMPASS parameters. The first one was a tensile test on a SWCNT, leading to a Young's modulus of 1.4 TPa at 300K. The second one was a pull-out test of a SWCNT from an originally uncured EPON 862/DETDA matrix.

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