With the decline in oil discoveries during the last decades it is believed that EOR technologies will play a key role to meet the energy demand in years to come. This paper presents a comprehensive review of EOR status and opportunities to increase final recovery factors in reservoirs ranging from extra heavy oil to gas condensate. Specifically, the paper discusses EOR status and opportunities organized by reservoir lithology (sandstone and carbonates formations and turbiditic reservoirs to a lesser extent) and offshore and onshore fields. Risk and rewards of EOR methods including growing trends in recent years such as CO 2 injection, high pressure air injection (HPAI) and chemical flooding are addressed including a brief overview of CO 2 -EOR project economics.
A crude oil and a synthetic reservoir water are used to prepare water-in-oil emulsions. The droplet-size distribution of water-in-oil emulsions is measured by digitally processing optical micrographs. The time evolution of the droplet-size distribution is used as a proxy of emulsion stability. A procedure for obtaining homogeneous aliquots of the initial emulsion is developed. The procedure yields statistical replicas of the initial sample that allow one to measure size distributions through direct observation of optical micrographs for a period of time of up to 7 days. The synthetic reservoir water is diluted by the addition of distilled water to determine how the water ionic strength affected emulsion stability. A detailed dropletsize distribution analysis supports the log-hyperbolic distribution as a better fit to the experimental observations than the Weibull or log-normal distributions. The inferred qualitative rates of coalescence indicate that emulsions are more stable at lower ionic strength of the aqueous phase. This result is consistent with previous emulsion characterization using electrorheology and bottle tests, demonstrating the importance of often overlooked aqueous-phase composition.
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