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Abstract.Compounds of the series LixLa(2_xv3TiO3 (x = 0.14, 0.23, 0.32, 0.35) as well as materials which are substituted with Pr, Tb, Cr and Fe were investigated by the coulometric titration method. The equilibrium potential as a function of 5Li as determined by the coulometric titration measurements was fitted using the random solution model which takes into account the ionic configurational entropy and the electronic contributions to the chemical potential of lithium.

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