Influence of weathering effect in natural environment on thermal properties hybrid kenaf blast/glass fibre and unsaturated polyester composite M Mohammed, A R Rozyanty, B O Beta et al. (10, 20, 30, 40,and 80 wt.%) using mechanical blending method. The blends were cured at room temperature using methyl ethyl ketone peroxide (MEKP) (4 wt.%) as catalyst initiator without the presence of catalystaccelerator. The effect of vinyl ester composition on theenhancement of mechanical and thermal properties of unsaturated polyester/vinyl ester blends was investigated.The polymer blends were characterized by Fourier Transform Infra Red (FTIR)spectroscopy, tensile testing, hardness testing, scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). IR spectra showed UP and VE peaks. The curing copolymerization reactionoccurred at vinyl (C=C) bonds. The addition of vinyl esters enhanced mechanical and thermal properties. The UP/VE blends showed homogeneous morphology, transparent and copolymer thermoset blend.Keywords: unsaturated polyester, vinyl ester, polymer blend, thermal properties
IntroductionUnsaturated polyester is a widely used thermosetting resin. Unsaturated polyester has a reactive vinyl (carbon-carbon double) bond. Styrene is added to unsaturated polyester as asolvent and acrosslinking agent for curing reaction. The organic peroxide is used to initiatethe reaction. Organic salt isadded to accelerate the reaction. The polymer is achieved as a result of random condensation copolymerization reaction between styrene and unsaturated vinyl double bonds by free radical mechanismforming crosslinked network structure [1,2]. Unsaturated polyester is a resin (prepolymer) with low price, light weight, easy processing and water resistance. Unsaturated polyester commonly used in laminating resin, composites, coating, adhesive, microelectronic, aerospace, building, automotive, and shipbuilding. However, unsaturated polyester shows limited mechanical and thermal properties. It is necessary to enhance the properties of unsaturated polyester.The properties of unsaturated polyester have been enhanced by theadditionof carbon fiber , fly ash, carbon nanotube, and polyamide [3][4][5][6]. Vinyl ester is an attractivehigh-performance thermoset polymer. Vinylester has reactive double bonds with rigid epoxy structure. Vinyl ester is synthesized by the reaction of epoxy with methacrylic