Fatty acid methyl esters (FAMEs) are sustainable biofuel that can alleviate high oil costs and environmental impacts of petroleum-based fuel. A modified 1200 W high-efficiency food blender was employed for continuous transesterification of various refined vegetable oils and waste cooking oil (WCO) using sodium hydroxide as a homogeneous catalyst. The following factors have been investigated on their effects on FAME yield: baffles, reaction volume, total reactant flow rate, methanol-oil molar ratio, catalyst concentration and reaction temperature. Results indicated that the optimal conditions were: 2000 mL reaction volume, 50 mL/min total flow rate, 1% and 1.25% catalyst concentration for refined palm oil and WCO, respectively, 6:1 methanol-to-oil molar ratio and 62–63 °C, obtaining yield efficiency over 96.5% FAME yield of 21.14 × 10–4 g/J (for palm oil) and 19.39 × 10–4 g/J (for WCO). All the properties of produced FAMEs meet the EN 14214 and ASTM D6751 standards. The modified household food blender could be a practical and low-cost alternative biodiesel production apparatus for continuous biodiesel production for small communities in remote areas.
Summary
Recovery of uranium from concentrated brine rejection from a small seawater reverse osmosis plant in Thailand using four types of the amidoxime adsorbents was experimentally performed. Adsorbents were directly submerged in continuously flowing discharged brine concentrate. Studied adsorbents were amidoximated polymer gel prepared from gamma irradiation, amidoximated polymer gel prepared from UV radiation curing, amidoximated polyacrylonitrile fibers, and chromic‐acid‐treated low‐density polyethylene fibers grafted with amidoxime functional group using gamma radiation. Uranium concentration in brine concentrate and input seawater was analyzed to be 4.8 and 3.1 ppb, respectively. Gel adsorbent synthesized by gamma irradiation exhibited the highest uranium loading capacity of 1.39 mg/g‐ad with 20 000 L/h rejected brine flow‐rate after 6 weeks of soaking. The estimated uranium recovery cost is 406.81 USD/kg uranium. If the adsorption capacity was increased to 2 mg/g‐ad, the projected cost was reduced to 338.95 USD/kg. Under this land‐based recovery scheme, no work is performed in an open ocean environment, thus, ensuring safety and reducing cost and time, especially the costs associated with ships, personnel, and diesel fuel to bring the materials to the ocean and back to the shore. The present study demonstrates that direct uranium recovery from discharged brine concentrate is possible using amidoxime‐based adsorbents developed to study uranium extraction from natural seawater. This should pave the way for further experimental studies in larger seawater reverse osmosis (SWRO) plants for the possible future energy source. A proposed large‐scale, yet very simple, deployment strategy at a hypothetical SWRO plant is also presented.
Novelty statement
Successful uranium adsorption by directly submerging adsorbents in continuously flowing discharged brine concentrate from seawater reverse osmosis plant
Mooring and recovery costs largely eliminated because of land‐based deployment
Highest uranium uptake capacity of 1.39 mg/g adsorbent after 6 weeks of soaking
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