In this study, the ultra-thin iron phosphate Fe7(PO4)6 nanosheets (FP1) with fine-controlled morphology, has been designed as a new two-dimensional (2D) material for uranium adsorption. Due to its unique high accessible 2D structure, atom-dispersed phosphate/iron anchor groups and high specific surface area (27.77 m2·g−1), FP1 shows an extreme-high U(VI) adsorption capacity (704.23 mg·g−1 at 298 K, pH = 5.0 ± 0.1), which is about 27 times of conventional 3D Fe7(PO4)6 (24.51 mg·g−1-sample FP2) and higher than most 2D absorbent materials, showing a great value in the treatment of radioactive wastewater. According to the adsorption results, the sorption between U(VI) and FP1 is spontaneous and endothermic, and can be conformed to single molecular layer adsorption. Based on the analyses of FESEM, EDS, Mapping, FT-IR and XRD after adsorption, the possibile adsorption mechanism can be described as a Monolayer Surface Complexation and Stacking mode (MSCS-Mode). Additionally, the research not only provide a novel preparing method for 2D phosphate materials but also pave a new pathway to study other two-dimensional adsorption materials.

Hydrogen-bonded PBSeT copolyesters are synthesized by introducing a polar amide unit into the molecular chain by adding decyldiamine. Two-step esteri cation and one-step polycondensation melt polymerization were adopted. ATR-FTIR and 1HNMR demonstrated the successful introduction of the amide unit. The effect of adding an amide unit on many properties was also discussed. Due to the formation of hydrogen bond, the force of the molecular chain is increased, the crystallinity is increased by 5.91%, and the yield strength and tear strength are increased by 40.7% and 74.8%, respectively. The addition of 1,10-decyldiamine has no signi cant effect on the glass transition temperature and thermal stability of polyester. The introduction of an amide unit decreased free volume and increased combined crystallinity, which also increased the water vapor barrier. At the same time, PBSeT copolyester still maintained its biodegradability under hydrolysis and enzymatic hydrolysis. This paper discusses a synthesis method of PBSeT copolyester strengthened by a hydrogen bond. The modi ed material has higher crystallinity, better mechanical properties, and a better water vapor barrier while maintaining certain biodegradation ability. It can be used in disposable products, food packaging, and other elds.

The development of more efficient and sustainable methods for synthesizing substituted urea compounds and directly utilizing CO2 has long been a major focus of synthetic organic chemistry as these compounds serve critical environmental and industrial roles. Herein, we report a green approach to forming the urea compounds directly from CO2 gas and primary amines, triggered by oxygen electroreduction in ionic liquids (ILs). These reactions were carried out under mild conditions, at very low potentials, and achieved high conversion rates. The fact that O2 gas was utilized as the sole catalyst in this electrochemical loop, without additional reagents, is a significant milestone for eco-friendly syntheses of C–N compounds and establishes an effective and green CO2 scavenging method.

Auricularia auricula, one of the most important edible mushrooms, is affected heavily by Trichoderma. We collected the diseased samples from the main A.auricula cultivation regions to characterize the pathogen and study the effect of Trichoderma spp. on A.auricula species. We identified one Trichoderma species, T.pleuroticola, based on the internal transcribed spacer and morphology characteristics and two types of A.auricula strains, Heiwei 15 (HW 15) and Hei 29 (H 29) were tested in this work. The growth rate of T.pleuroticola was 3.26–3.52 times higher than that of A.auricula and advantageously competed for living space and nutrients. In confrontation culture, T.pleuroticola completely inhibited the mycelium growth of A.auricula and grew on it, resulting in the diverse impact on HW 15 and H 29. In addition, T.pleuroticola can produce metabolites with antibacterial activity. The inhibition rate of volatile metabolites to H-29 and HW 15 was 13.46% and 10.44%, and the inhibition rate of nonvolatile metabolites to H-29 and HW 15 was 36.04% and 31.49%, respectively. These antifungal activities of inhibiting the growth of A.auricula were abbtributed to the organic compounds from T.pleuroticola, nonanal, tyrosine, beta-sitosterol, and wortmannin, which were identified by gas chromatography-ion mobility spectroscopy (GC-IMS) and liquid chromatography-mass spectrometry (LC-MS/MS). In short, T. pleuroticola was a highly pathogenic fungi in the production of A.auricula.

Auricularia auricula, one of the most important edible mushrooms, is affected heavily by Trichoderma. We collected the diseased samples from the main A.auricula cultivation regions to characterize the pathogen and study the effect of Trichoderma spp. on A.auricula species. We identified one Trichoderma species, T.pleuroticola, based on the internal transcribed spacer and morphology characteristics and two types of A.auricula strains, Heiwei 15 (HW 15) and Hei 29 (H 29) were tested in this work. The growth rate of T.pleuroticola was 3.26-3.52 times higher than that of A.auricula and advantageously competed for living space and nutrients. In confrontation culture, T.pleuroticola completely inhibited the mycelium growth of A.auricula and grew on it, resulting in a diverse impact on HW 15 and H 29. In addition, T.pleuroticola can produce metabolites with antibacterial activity. The inhibition rate of volatile metabolites to H-29 and HW 15 was 13.46% and 10.44%, and the inhibition rate of nonvolatile metabolites to H-29 and HW 15 was 36.04% and 31.49%, respectively. Further analysis showed that these antifungal activities inhibiting Auricularia auricula growth were mainly attributed to the organic compounds from T.pleuroticola, nonanal, tyrosine, beta-sitosterol, and wortmannin. In short, T. pleuroticola was a highly pathogenic fungi in the production of A.auricula.