Molecular-dynamics simulations suggest that in 2D screened Coulomb solids melt when the r.m.s. displacement of particles in local co-ordinate systems exceeds ∼ 10% of the lattice period, close to the Lindemann criterion in 3D. This criterion is over-estimated in the co-operative motion model, but under-estimated in the Einstein model, because during melting a 2D solid is a mixture of both ordered and disordered phases.
We introduce a simple empirical rule wherein the pairing interaction in superconductors is cancelled when normal and umklapp phonon scattering coexist. Superconductivity then arises solely from the residual umklapp contribution. As a result the deduced electron-phonon interactions in niobium, tantalum, lead and aluminum become virtually identical in the normal and superconducting states. Transition temperatures calculated under the rule are accurate within a few per cent when compared with experimental data. Features of the Matthias relations are also explained. The high T c so far predicted for metallic hydrogen is probably overly optimistic.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.