Efficient water splitting requires highly active, earth-abundant, and robust catalysts. Monometallic phosphides such as NiP have been shown to be active toward water splitting. Our theoretical analysis has suggested that their performance can be further enhanced by substitution with extrinsic metals, though very little work has been conducted in this area. Here we present for the first time a novel PH plasma-assisted approach to convert NiCo hydroxides into ternary NiCoP. The obtained NiCoP nanostructure supported on Ni foam shows superior catalytic activity toward the hydrogen evolution reaction (HER) with a low overpotential of 32 mV at -10 mA cm in alkaline media. Moreover, it is also capable of catalyzing the oxygen evolution reaction (OER) with high efficiency though the real active sites are surface oxides in situ formed during the catalysis. Specifically, a current density of 10 mA cm is achieved at overpotential of 280 mV. These overpotentials are among the best reported values for non-noble metal catalysts. Most importantly, when used as both the cathode and anode for overall water splitting, a current density of 10 mA cm is achieved at a cell voltage as low as 1.58 V, making NiCoP among the most efficient earth-abundant catalysts for water splitting. Moreover, our new synthetic approach can serve as a versatile route to synthesize various bimetallic or even more complex phosphides for various applications.

Due to the broadcast nature of radio propagation, the wireless air interface is open and accessible to both authorized and illegitimate users. This completely differs from a wired network, where communicating devices are physically connected through cables and a node without direct association is unable to access the network for illicit activities. The open communications environment makes wireless transmissions more vulnerable than wired communications to malicious attacks, including both the passive eavesdropping for data interception and the active jamming for disrupting legitimate transmissions. Therefore, this paper is motivated to examine the security vulnerabilities and threats imposed by the inherent open nature of wireless communications and to devise efficient defense mechanisms for improving the wireless network security. We first summarize the security requirements of wireless networks, including their authenticity, confidentiality, integrity, and availability issues. Next, a comprehensive overview of security attacks encountered in wireless networks is presented in view of the network protocol architecture, where the potential security threats are discussed at each protocol layer. We also provide a survey of the existing security protocols and algorithms that are adopted in the existing wireless network standards, such as the Bluetooth, Wi-Fi, WiMAX, and the long-term evolution (LTE) systems. Then, we discuss the state of the art in physical-layer security, which is an emerging technique of securing the open communications environment against eavesdropping attacks at the physical layer. Several physical-layer security techniques are reviewed and compared, including information-theoretic security, artificial-noise-aided security, security-oriented beamforming, diversity-assisted security, and physical-layer key generation approaches. Since a jammer emitting radio signals can readily interfere with the legitimate wireless users, we also introduce the family of various jamming attacks and their countermeasures, including the constant jammer, intermittent jammer, reactive jammer, adaptive jammer, and intelligent jammer. Additionally, we discuss the integration of physical-layer security into existing authentication and cryptography mechanisms for further securing wireless networks. Finally, some technical challenges which remain unresolved at the time of writing are summarized and the future trends in wireless security are discussed.

In this paper, we explore the physical-layer security in cooperative wireless networks with multiple relays where both amplify-and-forward (AF) and decode-and-forward (DF) protocols are considered. We propose the AF and DF based optimal relay selection (i.e., AFbORS and DFbORS) schemes to improve the wireless security against eavesdropping attack. For the purpose of comparison, we examine the traditional AFbORS and DFbORS schemes, denoted by T-AFbORS and T-DFbORS, respectively. We also investigate a so-called multiple relay combining (MRC) framework and present the traditional AF and DF based MRC schemes, called T-AFbMRC and T-DFbMRC, where multiple relays participate in forwarding the source signal to destination which then combines its received signals from the multiple relays. We derive closed-form intercept probability expressions of the proposed AFbORS and DFbORS (i.e., considered (i.e., AF and DF), the traditional and proposed optimal relay selection approaches both achieve the diversity order M where M represents the number of relays. In addition, numerical results show that for both AF and DF protocols, the intercept probability performance of proposed optimal relay selection is strictly better than that of the traditional relay selection and multiple relay combining methods. P-AFbORS and P-DFbORS) as well as the T-AFbORS, T-DFbORS, T-AFbMRC and T-DFbMRC schemes in the presence of eavesdropping attack. We further conduct an asymptotic intercept probability analysis to evaluate the diversity order performance of relay selection schemes and show that no matter which relaying protocol isIndex Terms-Relay selection, physical-layer security, intercept probability, diversity order, cooperative wireless networks.

The fields of photovoltaics, photodetection and light emission have seen tremendous activity in recent years with the advent of hybrid organic-inorganic perovskites. Yet, there have been far fewer reports of perovskite-based field-effect transistors. The lateral and interfacial transport requirements of transistors make them particularly vulnerable to surface contamination and defects rife in polycrystalline films and bulk single crystals. Here, we demonstrate a spatially-confined inverse temperature crystallization strategy which synthesizes micrometre-thin single crystals of methylammonium lead halide perovskites MAPbX3 (X = Cl, Br, I) with sub-nanometer surface roughness and very low surface contamination. These benefit the integration of MAPbX3 crystals into ambipolar transistors and yield record, room-temperature field-effect mobility up to 4.7 and 1.5 cm2 V−1 s−1 in p and n channel devices respectively, with 104 to 105 on-off ratio and low turn-on voltages. This work paves the way for integrating hybrid perovskite crystals into printed, flexible and transparent electronics.

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