Solid electrolytes (SEs) with superionic conductivity and interfacial stability are highly desirable for stable all-solid-state Li-metal batteries (ASSLMBs). Here, we employ neural network potential to simulate materials composed of Li, Zr/Hf, and Cl using stochastic surface walking method and identify two potential unique layered halide SEs, named Li 2 ZrCl 6 and Li 2 HfCl 6 , for stable ASSLMBs. The predicted halide SEs possess high Li + conductivity and outstanding compatibility with Li metal anodes. We synthesize these SEs and demonstrate their superior stability against Li metal anodes with a record performance of 4000 h of steady lithium plating/stripping. We further fabricate the prototype stable ASSLMBs using these halide SEs without any interfacial modifications, showing small internal cathode/SE resistance (19.48 Ω cm 2 ), high average Coulombic efficiency (∼99.48%), good rate capability (63 mAh g −1 at 1.5 C), and unprecedented cycling stability (87% capacity retention for 70 cycles at 0.5 C).
A new approach, steady micro air injection from the casing, is proposed to improve the stability of a three-stage low-speed axial compression system. Although the injection rate is designated to be only a few ten thousandth of the compressor flow rate, such an injection is able to trigger the unsteady response and thus lower the mass flow rate at stall for up to 5.83%. At the same time, it keeps the steady compressor characteristic with no injection unchanged. In order to verify that the compressor response is indeed unsteady, experiments at various injection configurations are performed, which include different injection angles, axial gaps between injector and blade leading edge, radial penetration of injector and the amount of injected air. Evidences of the unsteady response are further demonstrated through dynamic signal analysis using a wavelet-based method to show the behavior of early flow disturbances under the influence of injection. Numerical analyses performed at near stall condition show that the tip clearance vortices do response to the micro injection and thus delay the inception of stall.
A new approach, steady micro air injection from the casing, is proposed to improve the stability of a three-stage low-speed axial compression system. Although the injection rate is designated to be only a few ten thousandth of the compressor flow rate, such an injection is able to trigger the unsteady response and thus lower the mass flow rate at stall for up to 5.83%. At the same time, it keeps the steady compressor characteristic with no injection unchanged. In order to verify that the compressor response is indeed unsteady, experiments at various injection configurations are performed, which include different injection angles, axial gaps between injector and blade leading edge, radial penetration of injector and the amount of injected air. Evidences of the unsteady response are further demonstrated through dynamic signal analysis using a wavelet-based method to show the behavior of early flow disturbances under the influence of injection. Numerical analyses performed at near stall condition show that the tip clearance vortices do response to the micro-injection, and thus delay the inception of stall.
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