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Conducting an evaluation of the emergency management capacity of the chemical park and implementing targeted improvements based on the assessment results can significantly enhance the emergency preparedness and response capabilities of both the management departments and enterprises. This article proposes an emergency management capability assessment model for chemical parks based on PFDEMATEL (the Pythagorean fuzzy decision‐making trial and evaluation laboratory)‐G1 (the ordinal relation method) and PFTOPSIS (the Pythagorean fuzzy set TOPSIS). Firstly, based on the four stages of emergency management of chemical parks, emergency prevention, emergency preparedness, emergency response, and emergency recovery, an index system for evaluating the emergency management capacity of chemical parks was established. Secondly, PFDEMATEL is used to modify the G1 method to determine the index weight, so as to realize the objective rationality of the G1 method empowerment. On this basis, an emergency management capability evaluation model of chemical park to improve PFTOPSIS is proposed. Finally, taking three chemical parks as examples, the applicability of the evaluation model is verified. The research results can provide a theoretical reference for the emergency management decision‐making of governments and enterprises, improve the status quo of emergency management, and improve the prevention and handling capabilities of emergencies.