Scalable and cost-effective fabrication of threedimensional (3D) boron carbon nitride (BCN) microspheres was first demonstrated by hydrothermal and annealing methods. In particular, the specific surface area of 3D-BCN-4 reached 1390.12 m 2 g −1 and had a high hierarchical pore structure. An all-printed solid-state flexible microsupercapacitor (MSC) based on 3D-BCN-4 microspheres as an electrode material was fabricated for the first time by a screen printing method, which also provided efficacious properties. The single MSC areal capacitance reached 41.6 mF cm −2 . Furthermore, the remarkable mechanical flexibility was also achieved for the device with evidence that no obvious capacitance loss occurred even upon bending to 180°, and the device had a 93.3% capacitance retention after 1000 cycles. In addition, the maximum energy density reached 0.00832 mW h cm −2 , and the highest power density was 2 mW cm −2 . These results show the synthesis of 3D-BCN by a facile and effective method with excellent electrochemical performance, which should provide a promising direction to wearable energy storage devices.

The precise measurement of glucose level is significant for the health management of the human body. However, the existing sensitive materials and detection methods for glucose are less satisfying for practical applications. Herein, an ultrathin reticular two-dimensional nanosheets array composed of trimesic acid (H 3 BTC)-based bimetal metal−organic frameworks (MOFs) and carbon cloth (CC), which is constructed through a morphology control strategy, is reported for glucose sensing. Meanwhile, this nonmoving sweat glucose sensor based on a NiCo-BTC/CC electrode has been successfully prepared by a screen printing method. Benefiting from the regular and ultrathin nanosheets array, the NiCo-BTC/CC electrode has an excellent sensitivity of 2701.29 μA mM −1 cm −2 , which is about 2.4 times that of its unregulated counterpart (1127.85 μA mM −1 cm −2 ) in the linear range 5−205 μM. In addition, an ultralow detection limit (0.09 μM, S/N = 3) and good selectivity of NiCo-BTC/CC were also obtained. The high sensitivity of the glucose sensor based on NiCo-BTC/CC electrode is 0.174 μA μM −1 (50−1000 μM). Remarkably, the preciously designed sensor is used to detect glucose concentration in sweat with a noninvasive mode, and the results are basically consistent with those of a commercial glucose device with an invasive mode. This research exhibits potential methodology for the morphology design of bimetallic MOFs nanosheets to achieve a high accuracy rate and noninvasive and timeless measurement of a glucose sensor.

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Ultra-thin 2D bimetallic organic framework nanosheets were fabricated as electrode materials for flexible wearable power sources and non-invasive blood glucose monitoring.