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The β‐nucleating activity and toughening effect of acrylonitrile–butadiene–styrene (ABS) graft copolymer on isotactic polypropylene (iPP) and the compatibilizing role of maleic anhydride grafted polypropylene (PP‐g‐MAH) on the iPP/ABS blends were investigated. The results show that ABS can induce the formation of β‐crystal in iPP, and its β‐nucleating efficiency depends on its concentration and dispersibility. The relative content of β‐crystal form is up to 36.19% with the addition of 2% ABS. The tensile and impact properties of the iPP were dramatically enhanced by introducing ABS. The incorporation of PP‐g‐MAH into the iPP/ABS blends inhibits the formation of β‐crystal. The crystallization peaks of the blends shift toward higher temperature, due to the heterogeneous nucleation effect of PP‐g‐MAH on iPP. The toughness of iPP/ABS blends improved due to favorable interfacial interaction resulting from the compatibilization of PP‐g‐MAH is significantly better than the β‐crystal toughening effect induced by ABS. POLYM. ENG. SCI., 59:E317–E326, 2019. © 2019 Society of Plastics Engineers

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The influence of poly(acrylonitrile–butadiene–styrene) (ABS) as a special β-nucleating agent on the impact and tensile properties of isotactic polypropylene (iPP) were investigated by dynamic rheological measurements, wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and mechanical properties tests. It is found that the β nucleation efficiency of ABS is closely related to its concentration, dispersibility, and molding method for the iPP/ABS blends. The content of β-crystal (Kβ) rises with the incorporation of ABS and shows a maximum with the introduction of 1% ABS for compression-molded blends and 2% ABS for injection-molded blends, respectively, which is followed by a decrease in Kβ. The addition of a small amount of ABS has a significant reinforcing and toughening effect on iPP. Compared with the compression-molded samples, the ABS dispersed phase in injection-molded samples has a smaller particle size and a larger specific surface area, which are favorable for stress transmission and higher β nucleation efficiency, and therefore, better tensile and impact properties can be expected.

One-dimensional nanostructured SnO2 has attracted intense research interest due to its advantageous properties, including a large surface-to-volume ratio, high optical transparency and typical n-type properties. However, how to fabricate high-performance and multifunctional electronic devices based on 1D nanostructured SnO2 via low-cost and efficient preparation techniques is still a huge challenge. In this work, a low-cost, one-step electrospun technology was employed to synthesize the SnO2 nanofiber (NF) and nanotube (NT) arrays. The electrical and photoelectrical parameters of SnO2 NTs-based devices were effectively controlled through simple changes to the amount of Sn in the precursor solution. The optimal 0.2 SnO2 NTs-based field effect transistors (FETs) with 0.2 g SnCl2*4H2O per 5 ml in the precursor solution exhibit a high saturation current (∼9 × 10−5 A) and a large on/off ratio exceeding 2.4 × 106. Additionally, 0.2 SnO2 NTs-based FET also exhibit a narrowband deep-UV photodetectivity (240–320 nm), including an ultra-high photocurrent of 307 μA, a high photosensitivity of 2003, responsibility of 214 A W−1 and detectivity of 2.19 × 1013 Jones. Furthermore, the SnO2 NTs-based transparent photodetectors were as well be integrated with fluorine-doped tin oxide glass and demonstrated a high optical transparency and photosensitivity (∼199). All these results elucidate the significant advantages of these electrospun SnO2 NTs for next-generation multifunctional electronics and transparent photonics.