No abstract

We show that a frequency-resolved optical gating device using (1) a thick nonlinear crystal to replace the usual thin crystal and spectrometer and (2) a Fresnel biprism to replace the beam splitter and delay line yields a remarkably simple single-shot ultrashort-pulse intensity-and-phase measurement device with no sensitive alignment parameters and significantly greater sensitivity.

The electric field of an ultrashort laser pulse often fails to separate into a product of purely temporal and purely spatial factors. These so-called spatio-temporal couplings constitute a broad range of physical effects, which often become important in applications. In this review, we compile some recent experimental and theoretical work on the understanding, avoidance and applications of these effects. We first present a discussion of the characteristics of pulses containing spatio-temporal couplings, including their sources, a mathematical description and the interdependence of different couplings. We then review different experimental methods for their characterization. Finally, we describe different applications of spatio-temporal couplings and suggest further schemes for their exploitation and avoidance.

The steering of electron motion in molecules is accessible with waveform-controlled few-cycle laser light and may control the outcome of light-induced chemical reactions. An optical cycle of light, however, is much shorter than the duration of the fastest dissociation reactions, severely limiting the degree of control that can be achieved. To overcome this limitation, we extended the control metrology to the midinfrared studying the prototypical dissociative ionization of D(2) at 2.1 μm. Pronounced subcycle control of the directional D(+) ion emission from the fragmentation of D(2)(+) is observed, demonstrating unprecedented charge-directed reactivity. Two reaction pathways, showing directional ion emission, could be observed and controlled simultaneously for the first time. Quantum-dynamical calculations elucidate the dissociation channels, their observed phase relation, and the control mechanisms.