In order to study the influence of moisture on the interface of crumb rubber–asphalt (CR) mixture, the interface bonding performance and crack resistance of a crumb rubber–asphalt mixture under dry and wet conditions were studied at three scales. At the macroscale, the characteristics of medium temperature fatigue cracking and low temperature fracture were studied by semi-circular bending tensile test (SCB) on the example of digital image correlation (DIC) technique. At the microscale, the surface energy of CR with basalt and limestone was measured using the contact angle measurement test, and then the adhesion work was calculated and analyzed. At the molecular scale, the model of CR, the model of basalt representative mineral (augite) and limestone representative mineral (calcite) were studied by molecular dynamics simulation. The relationship between these three scales was further explored to reveal the mechanism of the damage of moisture on the interface deterioration of the CR mixture. The results show that moisture has a certain effect on the interface of the CR mixture, which is characterized by macroscopically reducing the crack resistance of the asphalt mixture, microscopically reducing the adhesion ability between the asphalt and the aggregate and weakening the interaction between the asphalt and aggregate molecules at the molecular scale. Molecular dynamics can accurately simulate the deterioration of micro asphalt-aggregate adhesion under the damage of moisture. The decrease in microadhesion leads to the decrease in the crack resistance of the macro-CR mixture.

In order to explore the variation of crumb rubber modified asphalt (CR) before and after aging at the micro- and nanoscales, the molecular dynamics simulation and atomic force microscopy (AFM) asphalt microstructure scanning were carried out on CR before and after aging. The molecular dynamics energy, radial distribution function (RDF), surface microstructure image, roughness, and other test results of the CR before and after aging were compared and analyzed. The results show that the molecular dynamic energy of the CR after aging increases; the asphaltene-asphaltene RDF is decreased after aging; and the AFM surface microstructure images of asphalt before and after aging do not change significantly, but quantitative analysis by roughness theory shows that aging makes the microscopic surface of the CR more uniform and gentle. By analyzing the changes of asphalt properties before and after aging at two scales, it can be found that there is a certain relationship between the properties obtained at different scales. The reasons and mechanisms for the influence of microstructure on aging are obtained by analyzing this relationship.