The characteristics of landfilled municipal solid waste have great influence on the design, operation, and management of landfills, affecting settlement, slope stability, and leachate/gas well integrity. Through analysis and study we observed that the landfill method is widely used to dispose of municipal solid waste (MSW), especially in developing countries. The research results of MSW landfill properties are different due to waste inhomogeneity. In this paper, MSW physical composition, unit weight, and permeability coefficient of landfills in several countries were reviewed and discussed. Landfilled MSW has strong regional and temporal characteristics. Landfilled MSW of developing countries has high organic content ranges from 75.00% to 97.15%. The organic contents in landfills of most developed regions are relatively small. The unit weight ranged from 4.9-17.8 kN/m 3 and the permeability coefficient ranged from 3.5×10-2 cm/sec to 5.0×10-8 cm/sec within 60 m. In the process of waste degradation, MSW physical composition, unit weight, and permeability coefficient are changed. Waste classification improves the recovery and utilization of landfill and reduces the amount of waste, which affects the characteristics of landfilled MSW. Thus, strengthening waste classification, recycling, and recovery of MSW is significant and meaningful for construction, operation, and management of landfills.

The research of seepage and stability in landfills may provide a less costly way to reduce accidents. Landslides often occur in the Jiangcungou Landfill because of the high leachate level. Some measures should be implemented to reduce the leachate level. This paper investigated seepage and slope stability of landfills by numerical methods. These results may provide the basis for increasing stability of landfills.

Landfilled municipal solid waste has evident heterogeneity, and clogging of the drainage layer can easily happen during operation of the landfill. These two factors significantly influence the distribution of leachate in a landfill. Herein, the distribution of waste permeability in the spatial and temporal domains was analyzed. Then, changes to the drainage-layer permeability in the temporal domain were fitted to these data. A simple model of multilayer waste slope was established combining the finite element software and a user subroutine. Herewith, changes of permeability in the waste and drainage layers were simulated, such that the heterogeneity of waste and the process of clogging of the drainage layer could be simulated. Then, the leachate distributions and transport conditions of nine schemes for landfill were analyzed. The results indicated that the distribution curve of waste-saturated permeability follows a logarithmic relation in the vertical direction, and the distribution curve of fresh-waste-saturated permeability follows a polynomial relation in time. After each landfill is worked for a few years, the drainage layer always encounters clogging problems of some kind and its permeability decreases by one to five orders of magnitude. Through numerical models, the simulation results of the permeability distribution in the spatial and temporal domains were found satisfactory. When the permeability distributions were layered in the buried depth, pore pressures and leachate levels are smaller than the logarithmic distributions. During the process of degradation, the pore pressures and leachate levels are increased slightly under the consideration of the polynomial distribution of waste permeability in time. With clogging of the permeability of the drainage layer, the pore pressures and leachate levels of landfill were found to be increasing gradually. To obtain results closer to that of actual situations, corresponding models should be established and analyzed based on a range of permeability, waste degradation rate, and degree of clogging.

No abstract

A novel calix [4]arene-based tetracholesteryl derivative was synthesized, and its gelation behaviours in 30 organic solvents were studied. It showed that 1 gelled long chain alkane, some of alcohol, kerosene, ethyl acetate benzene and toluene. Interestingly the gel of 1/kerosene possessed special property, which was that the mixture solution of the compound 1/kerosene heating for a while was put on the flat contact heater and formed a gel film at 25 C and 65 C. Unlike ordinary film, gel film had higher strength and toughness at 65 C, by contrast other was fragile and broken easily at 25 C, this phenomenon was few reported before. In order to explore the phenomenon, the mechanism of the gel of 1/kerosene was discussed by Scanning Electron Microscope (SEM), High Nuclear Magnetic Resonance (H NMR), Fourier Transform Infrared Spectrometer (IR) and micro-rheology. SEM revealed that the xerogel of 1/kerosene assembled network through some long and thick fibers at 65 C, with concentration reducing fibers become thin and its networks were clearly observed. In contrast the morphology of xerogel was porous at low concentration and was a bulk at high temperature system.According to EI data in micro-rheology, the gelation process could be divided into three stages at 65 C and they could be that some cholesterol segments in the gelator interacting with each other formed some small aggregation in the first stage, and other cholesterol section of the gelator sufficiently were cross-linked with time and assembled into large assembly in the second plateau. In the final moment the large assembly build gel network and the system of gel tended to stable. But there are two stages at low temperature and could be some cholesterol segments that didn't take part in assembly, which may be the cause that the performance of gel was fragile.