The major component of fused potassium silicate (FPS) fertilizers, produced from steel-making slag, was studied. FPS compounds have received considerable attention as slow-release potassium fertilizers beneficial for crops. This major component was found to be a single phase compound, K2Ca2Si2O7, which had not been previously identified. In order to confirm the presence of the newly identified compound, we synthesized a potassium calcium silicate mixture, K2O-2CaO-2SiO2, by fusing a mixture of K2CO3, CaCO3, and SiO2. The X-ray diffraction patterns of the synthesized K2O-2CaO-2SiO2 were largely consistent with those of FPS fertilizer, and Energy Dispersive X-ray Spectroscopy indicated that this compound was a single phase with a K:Ca:Si molar ratio of 1:1:1. It is concluded that the major component of FPS fertilizer is a compound of K2O-2CaO-2SiO2, newly identified as K2Ca2Si2O7. FPS fertilizers exhibit the characteristic, controlled by their K2Ca2Si2O7 content, of slowly releasing potassium into water and soil.KEY WORDS: steel-making slag; fused potassium silicate fertilizer; slow-release; single phase compound; potassium calcium silicate.
Simultaneous CO2 removal with renewable biofuel production can be achieved by methanogens through conversion of CO2 and H2 into CH4. However, the low gas–liquid mass transfer (kLa) of H2 limits the commercial application of this bioconversion.
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