Thermoelectric properties of SrTiO3doped with 8%Pm at Sr site were investigated using density functional theory and generalized gradient approximation. The transport properties were calculated based on BoltzTraP code at temperature range 300-1200K. In electronic properties study Fermi level were shifted to conduction band region due to high contribution 4f orbital in Pm. Present study thermoelectric figure of merit ZT result was 0.395 at 300K and 0.638 at 1200K. This shows a considerably good value of ZT for SrTiO3as n-type oxide. Compared to previous work, ZT were at the range of 0.21 - 0.37 for temperature of 300-1000K in Pr, La, Ta and Ho.
This research studied the effect of sodium bicarbonate content on the properties of epoxy. Sodium bicarbonate (SB) was used as foaming agent to improve the properties of thermosetting epoxy resin. The samples of epoxy foam were produced using mixing method. Sodium bicarbonate was selected as blowing agent by reason of the environmental friendly and low cost concern. Mechanical, physical and morphology properties were done. Sodium bicarbonate content was varied at 5, 10, 15, 20 and 25 part per hundred (phr), respectively. It can be highlighted that the optimum content of the SB was selected at 15 phr and it gave the moderate porosity percentage (%), and moderate value in mechanical and density properties, higher SB content exhibited lower flexural properties.
Polymer blend consist of epoxy and polymethylmethacrylate (PMMA) was prepared via two different blending methods. Conventional blending method which required solvent to obtain polymer blend of PMMA and epoxy. However, due to the high consumption of solvent and environmental issue, a new approaching method: direct mixing method was used to prepare the polymer blend without the usage of solvent. The PMMA pellets are grinded and sieved into fine powders and incorporated into epoxy. Comparison between the conventional and new method was done through the investigation based on the morphology and mechanical behaviour, with different PMMA content (0, 10, 20, 30, 40 and 50 vol.%) between two blending methods. In overall, the polymer blend system prepared via direct mixing methods exhibited better mechanical properties as compared to conventional solvent dissolution method. Improvement on fracture toughness was observed in direct mixing method.
The effects of Zn and Cu on the thermoelectric properties of ferrite thin films were studied in this paper. The Zn-Cu ferritethin film was fabricated using ink-jet printing method. A minimum of 50 print cycles was required to obtain continuous film with approximately 9 μm thick thin films. The thickness of Zn-Cu ferrite thin films was decreased with increasing sintering temperature from 200 oC (9.21 μm) to 400 oC (5.48 μm). The XRD traces of ZnxCu1-xFe2O4 exhibit as plane reflection for cubic spinel phase of ZnxCu1-xFe2O4 and there were no impurity peaks detected with increasing Zn content and sintering temperature. The electrical conductivity of ZnxCu1-xFe2O4 thin film decreased from 1.18x10-3 S/cm (x=0.0) to 0.48x10-3 S/cm (x=1.0) with increasing Zn content. Positive Seebeck values were observed for all the samples, which indicated the samples were p-type. The Seebeck coefficient of ZnxCu1-xFe2O4 thin film increased from 6.36 μV/K (x=0.0) to 17.46 μV/K (x=1.0) with increasing Zn content.
The search for clean energy conversion technologies promotes the study of thermoelectric materials. In this paper, the electronic structure and thermoelectric properties of CaMnO3 doped with 17% V using first principles calculations and semi-classic Boltzmann theory on Ca site as well as Mn sites. The G-type AFM magnetic ordering is most stable among four types of magnetic ordering for CaMnO3 and V doped CaMnO3 a Mn site while FM ordering was found for V doped CaMnO3 at Ca site. The calculated partial density of states plot shows half metallic and metallic behavior for V doped at A site and B site respectively. Thermoelectric property calculations show that the magnitude of Seebeck coefficient decreased with V doping at both sites with V doping at Mn sites has the lowest magnitude of Seebeck coefficient. All samples show the negative Seebeck coefficient indicating n type behavior. The magnitude of conductivity increases with V doping with the highest magnitude belong to V doped at Mn site. The magnitude of thermal conductivity also increased with V doping at Mn site, but shows a reduction for V doping at Ca site. The figure of merit (ZT) for V doping at Ca site shows a significant improvement over intrinsic CaMnO3 at 0.14 at 1000 K. However, V doping at Mn site sample shows a reduction of ZT at 0.0028 for CaMnO3 at 1000 K which is much lower than CaMnO3 at 0.08.
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