Copper nanowires (Cu NWs) are suitable material as an electrode for flexible, stretchable and wearable devices due to their excellent mechanical properties, high transparency, good conductivity, and low cost, but oxidation problem limits their practical use and application. In order to use Cu NWs as an electrode for advanced flexible, stretchable and wearable devices attached directly to the skin, the influence of the body temperature on the oxidation of Cu NWs needs to be investigated. In this paper, the oxidation behavior of Cu NWs at high temperature (more than 80 °C) as well as body temperature is studied which has been remained largely questionable to date, and an effective encapsulation method is proposed to prevent the oxidation of Cu NWs electrode in the range of body temperatures.
Copper nanowires (Cu NWs) have gained attention as an alternative to noble metal nanowires due to their affordable price, but their susceptibility to rapid oxidization in ambient conditions has remained a critical limitation for their practical usage. Many studies have been conducted to address this disadvantage but have been successful only in terms of oxidation prevention at certain temperatures, leaving the matter of oxidation at high temperatures unresolved. In this article, a simple encapsulation structure made of a polyimide and SiOx thin film is presented that effectively prevents the penetration of oxygen and moisture into the Cu NW network. This structure, furthermore, boasts excellent stability at high temperature (≈350 °C) and in underwater, acidic chemical, and abrasive conditions.
Inspired by the rolling mechanism of the proboscis of a butterfly, rollable electronics that can be rolled and unrolled to a great extent on demand are developed. Generally, electronic devices that are attached to various surfaces to acquire biosignals require mechanical flexibility and sufficient adhesive force. The rollable platform provides sufficient force that grips onto the entire target surface without destroying the target organ. To prove the versatility of our device not only in gripping and detecting biosignals from micro objects but also in performing a variety of functions, thin-film electronics including a heater, strain sensor and temperature sensor are constructed on the rollable platform, and it is confirmed that all the electronics operate normally in the rolled and unrolled states without breakdown. Then, micro bio-objects are gripped by using the rollable platform, and their tiny motions are successfully detected with the sensor on the platform. Furthermore, the detection of the pulse wave signals of swine under diverse experimental conditions is successfully conducted by rolling up the rollable system around the blood vessel of the swine, the result of which proves the feasibility of a rollable platform as a biomedical device.
Among many flexible mechanosensors, a crack-based sensor inspired by a spider’s slit organ has received considerable attention due to its great sensitivity compared to previous strain sensors. The sensor’s limitation, however, lies on its vulnerability to stress concentration and the metal layers’ delamination. To address this issue of vulnerability, we used fluorinated ethylene propylene (FEP) as an encapsulation layer on both sides of the sensor. The excellent waterproof and chemical resistance capability of FEP may effectively protect the sensor from damage in water and chemicals while improving the durability against friction.
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