The precursor for a lithium-ion sieve is prepared using an inorganic precipitation-peptization method with titanium sulfate as the titanium source and lithium acetate as the lithium source. The effects of Ni2+ (Nickel ions) doping on the stability of the sol, crystal morphology and interplanar spacing of Li2TiO3 are investigated. The results indicate that, after Ni2+ doping with varying fractions, the stability of the precursor sol first increases then decreases, and the maximum stabilization time of the precursor sol doped with 1% Ni2+ is 87 h. When doped with 1% Ni2+, the sol performance is most stable, the porous Li2TiO3 is obtained, and the specific surface area of Li2TiO3 increases by up to 1.349 m2/g from 0.911 m2/g. Accompanying the increase in calcination temperature, the inhibition of Ni2+ doping on the growth and crystallization of grains decreases. When the temperature is lower than 750 °C, Ni atoms replace the Ti atoms that are substituted for Li atoms in the original pure Li layer, forming lattice defects, resulting in the disappearance of (002) and (−131) diffraction peaks for Li2TiO3, the reduced ordering of crystal structure, a decrease in the interplanar spacing of the (002) plane, lattice expansion and an increase in the particle size to 100–200 nm. When the temperature exceeds 750 °C, with the increase of calcination temperature, the influence of Ni doping on the growth and crystallinity of grains decreases, and the (002) crystal surface starts to grow again.

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