The thermoelectric effect enables direct and reversible conversion between thermal and electrical energy, and provides a viable route for power generation from waste heat. The efficiency of thermoelectric materials is dictated by the dimensionless figure of merit, ZT (where Z is the figure of merit and T is absolute temperature), which governs the Carnot efficiency for heat conversion. Enhancements above the generally high threshold value of 2.5 have important implications for commercial deployment, especially for compounds free of Pb and Te. Here we report an unprecedented ZT of 2.6 ± 0.3 at 923 K, realized in SnSe single crystals measured along the b axis of the room-temperature orthorhombic unit cell. This material also shows a high ZT of 2.3 ± 0.3 along the c axis but a significantly reduced ZT of 0.8 ± 0.2 along the a axis. We attribute the remarkably high ZT along the b axis to the intrinsically ultralow lattice thermal conductivity in SnSe. The layered structure of SnSe derives from a distorted rock-salt structure, and features anomalously high Grüneisen parameters, which reflect the anharmonic and anisotropic bonding. We attribute the exceptionally low lattice thermal conductivity (0.23 ± 0.03 W m(-1) K(-1) at 973 K) in SnSe to the anharmonicity. These findings highlight alternative strategies to nanostructuring for achieving high thermoelectric performance.

Lesion analysis is a classic approach to study brain functions. Because brain function is a result of coherent activations of a collection of functionally related voxels, lesion-symptom relations are generally contributed by multiple voxels simultaneously. Although voxel-based lesion symptom mapping (VLSM) has made substantial contributions to the understanding of brain-behavior relationships, a better understanding of the brain-behavior relationship contributed by multiple brain regions needs a multivariate lesion symptom mapping (MLSM). The purpose of this paper was to develop an MLSM using a machine learning-based multivariate regression algorithm: support vector regression (SVR). In the proposed SVR-LSM, the symptom relation to the entire lesion map as opposed to each isolated voxel is modeled using a non-linear function, so the intervoxel correlations are intrinsically considered, resulting in a potentially more sensitive way to examine lesion-symptom relationships. To explore the relative merits of VLSM and SVR-LSM we used both approaches in the analysis of a synthetic dataset. SVR-LSM showed much higher sensitivity and specificity for detecting the synthetic lesion-behavior relations than VLSM. When applied to lesion data and language measures from patients with brain damages, SVR-LSM reproduced the essential pattern of previous findings identified by VLSM and showed higher sensitivity than VLSM for identifying the lesion-behavior relations. Our data also showed the possibility of using lesion data to predict continuous behavior scores.

The interannual relationship between the East Asian summer monsoon and the tropical Pacific SSTs is studied using rainfall data in the Yangtze River Valley and the NCEP reanalysis for 1951-96. The datasets are also partitioned into two periods, 1951-77 and 1978-96, to study the interdecadal variations of this relationship.A wet summer monsoon is preceded by a warm equatorial eastern Pacific in the previous winter and followed by a cold equatorial eastern Pacific in the following fall. This relationship involves primarily the rainfall during the pre-Mei-yu/Mei-yu season (May-June) but not the post-Mei-yu season (July-August). In a wet monsoon year, the western North Pacific subtropical ridge is stronger as a result of positive feedback that involves the anomalous Hadley and Walker circulations, an atmospheric Rossby wave response to the western Pacific complementary cooling, and the evaporation-wind feedback. This ridge extends farther to the west from the previous winter to the following fall, resulting in an 850-hPa anomalous anticyclone near the southeast coast of China. This anticyclone 1) blocks the pre-Mei-yu and Mei-yu fronts from moving southward thereby extending the time that the fronts produce stationary rainfall; 2) enhances the pressure gradient to its northwest resulting in a more intense front; and 3) induces anomalous warming of the South China Sea surface through increased downwelling, which leads to a higher moisture supply to the rain area. A positive feedback from the strong monsoon rainfall also appears to occur, leading to an intensified anomalous anticyclone near the monsoon region. This SST-subtropical ridge-monsoon rainfall relationship is observed in both the interannual timescale within each interdecadal period and in the interdecadal scale.The SST anomalies (SSTAs) change sign in northern spring and resemble a tropospheric biennial oscillation (TBO) pattern during the first interdecadal period . In the second interdecadal period (1978-96) the sign change occurs in northern fall and the TBO pattern in the equatorial eastern Pacific SST is replaced by longer timescales. This interdecadal variation of the monsoon-SST relationship results from the interdecadal change of the background state of the coupled ocean-atmosphere system. This difference gives rise to the different degrees of importance of the feedback from the anomalous circulations near the monsoon region to the equatorial eastern Pacific.In a wet monsoon year, the anomalous easterly winds south of the monsoon-enhanced anomalous anticyclone start to propagate slowly eastward toward the eastern Pacific in May and June, apparently as a result of an atmosphere-ocean coupled wave motion. These anomalous easterlies carry with them a cooling effect on the ocean surface. In 1951-77 this effect is insignificant as the equatorial eastern Pacific SSTAs, already change from warm to cold in northern spring, probably as a result of negative feedback processes discussed in ENSO mechanisms. In 1978-96 the equatorial eastern Pacific has ...

Observations were employed to study the thermal characteristics of the Tibetan Plateau and its neighboring regions, and their impacts on the onset of the Asian monsoon in 1989. Special attention was paid to the diagnosis of the temporal and spatial distributions of surface sensible and latent heat fluxes. Results show that the whole procedure of the outbreak of the Asian monsoon onset is composed of three consequential stages. The first is the monsoon onset over the eastern coast of the Bay of Bengal (BOB) in early May. It is followed by the onset of the East Asian monsoon over the South China Sea (SCS) by 20 May, then the onset of the South Asian monsoon over India by 10 June. It was shown that the onset of the BOB monsoon is directly linked to the thermal as well as mechanical forcing of the Tibetan Plateau. It then generates a favorable environment for the SCS monsoon onset. Afterward, as the whole flow pattern in tropical Asia shifts westward, the onset of the South Asian monsoon occurs. Finally, the timing of the onset of the Asian monsoon in 1989 was explored. It was shown that the onset of the Asian monsoon occurs when the warm or rising phase of different low-frequency oscillations reach the ''East Asian monsoon area'' (EAMA) concurrently. These include the warm phase of the eastward propagating twoto three-week oscillation (TTO) of the upper-layer temperature in middle latitudes, the rising phase of the northward propagating Madden-Julian oscillation of the southern tropical divergence, and the rising phase of the westward propagating TTO of the western Pacific divergence. It was concluded that the timing of the Asian monsoon onset is determined when the favorable phases of different low-frequency oscillations are locked over the EAMA.

The climatological mean summer monsoon onset in the South China Sea (SCS) is a remarkably abrupt event. However, defining onset dates for individual years is noticeably controversial. The controversies and complications arise primarily from a number of factors: the intermittent southward intrusion of cold fronts into the northern SCS, the bogus onset in late April before the establishment of tropical monsoons over Indochina, and active intraseasonal oscillation. In this paper, a simple yet effective index, U SCS , the 850-hPa zonal winds averaged over the central SCS (5Њ-15ЊN and 110Њ-120ЊE), is proposed for objectively defining the SCS monsoon onset. This onset index depicts not only the sudden establishment of the tropical southwesterly monsoon over the SCS but also the outbreak of the rainy season in the central-northern SCS.In this paper the East Asian summer monsoon (EASM) is defined as the broadscale summer monsoon over East Asia and the western North Pacific region (0Њ-40ЊN, 100Њ-140ЊE). It is shown that the seasonal transition of EASM can be objectively determined by the principal component of the dominant empirical orthogonal mode of the 850-hPa zonal winds, U EOF1 . It is found that the local index U SCS represents U EOF1 extremely well; thus, it can be used to determine both the SCS onset and the commencement of the broadscale EASM. The result suggests that the SCS summer monsoon onset indeed signifies the beginning of the summer monsoon over East Asia and the adjacent western Pacific Ocean. Evidence is also provided to show the linkage between the two salient phases of EASM: the local onset of the SCS monsoon and the local onset of the mei-yu (the rainy season in the Yangtze River and Huai River basin and southern Japan).