Various physical tweezers for manipulating liquid droplets based on optical, electrical, magnetic, acoustic, or other external fields have emerged and revolutionized research and application in medical, biological, and environmental fields. Despite notable progress, the existing modalities for droplet control and manipulation are still limited by the extra responsive additives and relatively poor controllability in terms of droplet motion behaviors, such as distance, velocity, and direction. Herein, we report a versatile droplet electrostatic tweezer (DEST) for remotely and programmatically trapping or guiding the liquid droplets under diverse conditions, such as in open and closed spaces and on flat and tilted surfaces as well as in oil medium. DEST, leveraging on the coulomb attraction force resulting from its electrostatic induction to a droplet, could manipulate droplets of various compositions, volumes, and arrays on various substrates, offering a potential platform for a series of applications, such as high-throughput surface-enhanced Raman spectroscopy detection with single measuring time less than 20 s.
Harvesting energy from water, in the form of raindrops, river, and ocean waves, is of considerable importance and has potential applications in self‐powered electronic devices and large‐scale energy needs. Recently, the droplet‐based electricity generator has shown an increase by several orders of magnitude in electrical output, overcoming the drawback of traditional droplet‐based device limited by interfacial effects. Despite this exciting result, the output performance of this novel droplet‐based electricity generator is limited by relatively low frequency of impinging droplets owing to the formation of a continuous liquid film at high impact frequency, which might hinder its practical applications. To overcome this challenge, here, we report the design of a superhydrophobic surface based droplet electricity generator, referred to as SHS‐DEG, which can timely shed water droplets from the surface without the formation of liquid film at high impact frequency, and thereby generating enhanced average electrical output. Moreover, our SHS‐DEG exhibits many distinctive advantages over conventional design including robustness, long‐term durability, and power generation stability even in harsh environments. We envision that the ability to harvest electrical energy from water droplets at high impact frequency has promising applications in various energy‐harvesting systems.
Ice propagation is of great importance to the accumulation of ice/frost on solid surfaces. However, no investigation has been reported on the tuning of ice propagation through a simple coating process. Herein, we study the ice propagation behavior on polyelectrolyte multilayer (PEM) surfaces coated with the layer-by-layer (LBL) deposition approach. We discover that ice propagation is strongly dependent on the amount of water in the outermost layer of PEMs, that is, the ice propagation rate increases with the amount of water in the outermost layer. The ice propagation rate can be tuned by up to three orders of magnitude by changing the polyelectrolyte pairs, counterions of the outermost polymer layer, or the salt concentration during the preparation of PEMs. Because the simple, versatile, and inexpensive LBL deposition approach is generally applicable to almost all available surfaces, the PEM coatings can tune ice propagation on a wide range of substrates.
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