The miniaturization and integration of frequency-agile microwave circuits--relevant to electronically tunable filters, antennas, resonators and phase shifters--with microelectronics offers tantalizing device possibilities, yet requires thin films whose dielectric constant at gigahertz frequencies can be tuned by applying a quasi-static electric field. Appropriate systems such as BaxSr1-xTiO3 have a paraelectric-ferroelectric transition just below ambient temperature, providing high tunability. Unfortunately, such films suffer significant losses arising from defects. Recognizing that progress is stymied by dielectric loss, we start with a system with exceptionally low loss--Srn+1TinO3n+1 phases--in which (SrO)2 crystallographic shear planes provide an alternative to the formation of point defects for accommodating non-stoichiometry. Here we report the experimental realization of a highly tunable ground state arising from the emergence of a local ferroelectric instability in biaxially strained Srn+1TinO3n+1 phases with n ≥ 3 at frequencies up to 125 GHz. In contrast to traditional methods of modifying ferroelectrics-doping or strain-in this unique system an increase in the separation between the (SrO)2 planes, which can be achieved by changing n, bolsters the local ferroelectric instability. This new control parameter, n, can be exploited to achieve a figure of merit at room temperature that rivals all known tunable microwave dielectrics.
We have studied the effect of tensile strain on the superconductivity in FeSe
films. 50 nm, 100 nm, and 200 nm FeSe films were grown on MgO, SrTiO$_3$, and
LaAlO$_3$ substrates by using a pulsed laser deposition technique. X-ray
diffraction analysis showed that the tetragonal phase is dominant in all of our
FeSe films. The 50 nm FeSe films on MgO and SrTiO$_3$ are under tensile strain,
while the 50 nm FeSe film on LaAlO$_3$ and the other thick FeSe films are
unstrained. Superconducting transitions have been observed in unstrained FeSe
films with T$_{onset}$ $\approx$ 8 K, which is close to the bulk value.
However, no sign of superconductivity has been observed in FeSe films under
tensile strain down to 5 K. There is evidence to show that tensile strain
suppresses superconductivity in FeSe films
We have directly measured the band gap renormalization associated with the Moss-Burstein shift in the perovskite transparent conducting oxide (TCO), La-doped BaSnO 3 , using hard x-ray photoelectron spectroscopy. We determine that the band gap renormalization is almost entirely associated with the evolution of the conduction band. Our experimental results are supported by hybrid density functional theory supercell calculations. We determine that unlike conventional TCOs where interactions with the dopant orbitals are important, the band gap renormalization in La-BaSnO 3 is driven purely by electrostatic interactions.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.