The
understanding of the shrinkage dynamics of plasmonic bubbles
formed around metallic nanoparticles immersed in liquid and irradiated
by a resonant light source is crucial for the usage of these bubbles
in numerous applications. In this paper, we experimentally show and
theoretically explain that a plasmonic bubble during its shrinkage
undergoes two different phases: first, a rapid partial bubble shrinkage
governed by vapor condensation and, second, a slow diffusion-controlled
bubble dissolution. The history of the bubble formation plays an important
role in the shrinkage dynamics during the first phase as it determines
the gas–vapor ratio in the bubble composition. Higher laser
powers lead to more vaporous bubbles, while longer pulses and higher
dissolved air concentrations lead to more gaseous bubbles. The dynamics
of the second phase barely depends on the history of bubble formation,
that is, laser power and pulse duration, but strongly on the dissolved
air concentration, which defines the concentration gradient at the
bubble interface. Finally, for the bubble dissolution in the second
phase, with decreasing dissolved air concentration, we observe a gradual
transition from a R(t) ∝
(t
0 – t)1/3 scaling law to a R(t) ∝
(t
0 – t)1/2 scaling law where t
0 is the lifetime
of the bubble and theoretically explain this transition.
Cold welding technique at room temperature is the preferred option in nanoassembly and nano-jointing. In this study, the cold welding behavior and mechanical strength of Cu 50 Zr 50 metallic glass nanowires (MGNWs) in head-tohead contact are investigated by molecular dynamics simulation based on the embedded atom method potential. Effects of welding velocity, operating temperature, and size of nanowires are discussed with the consideration of stress, shear strain, atomic deformation processes, and weld quality. Our simulation results demonstrate that a desirable weld quality can be obtained at room temperature. With an increase in welding velocity, the shear deformation zones of the welded MGNWs increase, leading to a decrease in mechanical strength. However, the effect of temperature on the weld quality is not pronounced. Besides, the elongation ability of the welded MGNWs increases with increasing diameters of nanowires. Smaller diameter results in better weld quality due to the size effect of metallic glass. For a pair of MGNWs with different diameters, the necking and fracture of the welded MGNWs occur in the regions of the nanowire with a relatively smaller diameter. This study carries major implications for the fabrication and structural assembly of metallic glass-based nanomaterials.
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