BackgroundCOVID-19-related anxiety, sleep problems, and loneliness may be risk factors for school refusal in children and adolescents. However, few studies have examined the mechanisms by which these risk factors cause school refusal. This study examined the process by which COVID-19-related anxiety, sleep problems, and loneliness cause school refusal, using structural equation modeling.MethodsIn this cross-sectional questionnaire-based study, 256 (109 male, 147 female, mean age: 15.37 ± 0.48 years) senior high school students were asked to complete the Stress and Anxiety associated with Viral Epidemics-6 questionnaire to assess COVID-19-related anxiety, the Athens Insomnia Scale (AIS), Sleep Debt Index (SDI), and chronotype (MSFsc) to assess sleep problems, the Three-Item Loneliness Scale (TILS) to assess loneliness, and Feelings of School-Avoidance Scale (FSAS) to assess school refusal.ResultsStructural equation modeling showed that sleep problems affected loneliness (β = 0.52) and feelings of school refusal (β = 0.37), and that loneliness affected feelings of school refusal (β = 0.47). There was no significant pathway of COVID-19-related anxiety on sleep problems, loneliness, or feelings of school refusal. The indirect effect of sleep problems on feelings of school refusal through loneliness was significant. The results of hierarchical multiple regression analysis showed that AIS (β = 0.30) and SDI (β = 0.13) scores were associated with TILS, and AIS (β = 0.26) and MSFsc (β = −0.14) scores were associated with FSAS scores.ConclusionThe findings of this study showed that sleep problems affected feelings of school refusal via both direct and indirect pathways through the exacerbation of loneliness. To prevent school refusal in adolescents, addressing the indirect pathway via loneliness could be effective in improving insomnia and sleep debt, while addressing the direct pathway could be effective in improving insomnia and chronotype.
The relationship between chemical states and optical properties for porous silicon (PS) under initial oxidation by heating at low temperatures (150, 200, 250 °C) in air was investigated using an infrared (IR) spectroscopy and photoluminescence (PL) measurements. The measurements in the IR region show that the IR absorption peaks for the Si-H stretching band (2050-2150 cm−1) change with appearance of the Si-O-Si-H stretching band (2100-2300 cm−1) when the thermal oxidation time is increased. On the other hand, the peak in the PL spectrum shows a blue shift from 820 nm to 710 nm with the oxidation time. The observed blue shift of the PL spectrum is due to the decrease in the initial PL peak intensity at 820 nm and the increase at 710 nm. Moreover, the peak intensities in the PL spectra at 820 nm and 710 nm have clear relationship to the amounts of the Si-H bonds and Si-O-Si-H bonds, respectively, as a function of the oxidation time.These results indicate that luminescence center (LC) for as-prepared PS is ascribed to complexes including Si-H bonds. Also the LC for oxidized PS under the oxidation process at low temperatures is ascribed to complexes including Si-O-Si-H bonds covering the inner surface of PS.
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