Exhaled breath samples from 60 volunteers (30 lung cancer patients, 30 healthy people), and headspace VOCs from lung cancer cells (A549 and H1703) were analyzed using proton-transfer-reaction mass spectrometry (PTR-MS).

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China is experiencing serious atmospheric pollution, which also exhibits significant spatial heterogeneity. The Chinese government has implemented targeted pollution control measures at the city level, emphasizing coordination among cities to prevent and control air pollution in key regions such as Beijing-Tianjin-Hebei (BTH) urban agglomeration. This study combined an inter-city multi-regional input-output (MRIO) model with an air quality dispersion model consisting of a weather research and forecasting (WRF) model and the CALPUFF model (WRF/CALPUFF) to study the inter-city economic consumption, pollutant emission and concentration among 13 cities in BTH urban agglomeration. NOx is chosen as an example. The combined effects of economic linkage and atmospheric transport show that NOx concentrations in cities in the BTH urban agglomeration are attributable to three consumption sources: a local contribution from the target city's own local economic consumption (average, 25%), and non-local consumption contributions, including other cities in the BTH urban agglomeration (average, 36%) and regions outside of BTH (average, 39%). Compared with the contributions to NOx concentrations calculated using only the MRIO model or atmospheric transport stimulation model, the results of this paper quantify that the consumption outside of a city could provide a greater impact on the city's air quality due to the combined effects of economic linkage and atmospheric transport. To avoid negative impacts of emission reduction targets on economic consumption, governmental regional pollution control policies should consider the combined effects of economic linkage and atmospheric transport.

We present a near-real-time global gridded daily CO2 emissions dataset (GRACED) throughout 2021. GRACED provides gridded CO2 emissions at a 0.1° × 0.1° spatial resolution and 1-day temporal resolution from cement production and fossil fuel combustion over seven sectors, including industry, power, residential consumption, ground transportation, international aviation, domestic aviation, and international shipping. GRACED is prepared from the near-real-time daily national CO2 emissions estimates (Carbon Monitor), multi-source spatial activity data emissions and satellite NO2 data for time variations of those spatial activity data. GRACED provides the most timely overview of emissions distribution changes, which enables more accurate and timely identification of when and where fossil CO2 emissions have rebounded and decreased. Uncertainty analysis of GRACED gives a grid-level two-sigma uncertainty of value of ±19.9% in 2021, indicating the reliability of GRACED was not sacrificed for the sake of higher spatiotemporal resolution that GRACED provides. Continuing to update GRACED in a timely manner could help policymakers monitor energy and climate policies’ effectiveness and make adjustments quickly.

Cities in China are on the frontline of low-carbon transition which requires monitoring city-level emissions with low-latency to support timely climate actions. Most existing CO2 emission inventories lag reality by more than one year and only provide annual totals. To improve the timeliness and temporal resolution of city-level emission inventories, we present Carbon Monitor Cities-China (CMCC), a near-real-time dataset of daily CO2 emissions from fossil fuel and cement production for 48 major high-emission cities in China. This dataset provides territory-based emission estimates from 2020-01-01 to 2021-12-31 for five sectors: power generation, residential (buildings and services), industry, ground transportation, and aviation. CMCC is developed based on an innovative framework that integrates bottom-up inventory construction and daily emission estimates from sectoral activities and models. Annual emissions show reasonable agreement with other datasets, and uncertainty ranges are estimated for each city and sector. CMCC provides valuable daily emission estimates that enable low-latency mitigation monitoring for cities in China.