Cu-Sn-Zn coatings have been widely used in industry for their unique properties, such as good conductivity, high corrosion resistance and excellent solderability. To further improve the mechanical performance of Cu-Sn-Zn coatings, powder-enhanced method was applied in the current study and Cu-Sn-Zn-TiO2 nanocomposite coatings with different TiO2 concentration were fabricated. The microstructure of Cu-Sn-Zn-TiO2 nano-composite coatings were investigated by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The mechanical properties of coatings including microhardness and wear resistance were studied. The results indicate that the incorporation of TiO2 nanoparticle can significantly influence the properties of Cu-Sn-Zn coatings. The microhardness of Cu-Sn-Zn coating was increased to 383 HV from 330 HV with 1g/L TiO2 addition. Also, the corrosion resistance of coating was enhanced. The effects of TiO2 nanoparticle concentration on the microstructure, mechanical properties and corrosion resistance of Cu-Sn-Zn-TiO2 nano-composite coatings were discussed.
A (Ni0.6Fe0.4)65B18Si10Nb4C3 amorphous composite coating has been fabricated on a mild steel substrate by a laser cladding process under different heat inputs. Observation of the structure and phase showed that the thickness of the coating decreased and the amorphous fraction increased when the laser cladding heat input was lower. The cooling rate increases when the heat input decreases, which favours the formation of amorphous phase. Microhardness and wear resistance test results indicated that a lower heat input led to higher microhardness and better wear resistance of the coating. An average microhardness of 1187.0 HV0.2 was obtained with a heat input of 69 J mm–1.
Cu-Sn-Zn (CSZ) coatings are widely applied in communication devices due to their excellent performance in electrical/thermal conductivity, solderability, and corrosion resistance. Particularly, a novel TiO 2 -sol-enhanced electrodeposition method has been proposed to prepare CSZ-TiO 2 nanocomposite coatings with different volume fractions of TiO 2 -sol. A series of CSZ-TiO 2 nanocomposite coatings were prepared in the current study. The crystal phase, surface morphology, and micro-to nanostructures of sol-enhanced nanocomposite coatings were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Based on the prior research, we studied the microhardness, surface friction behavior, and corrosion behavior of the coatings. Our results indicate that adding 12.5 mL L −1 TiO 2 -sol increased the average microhardness of CSZ coating from 325 to 421 HV and reduced the corrosion rate by 42.8%. Those results reveal that the TiO 2 -sol affected the performance of CSZ coatings depends on the volume added. Additionally, we investigated the effects of TiO 2 -sol volume fraction on the morphology, microhardness, dry sliding wear-resistant capability, and corrosion-resistant capability.
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