Microcapsules have attracted widespread interest for their unique properties in encapsulation, protection, and separation of active ingredients from the surrounding environment. However, microcapsule carriers with controllable shell thickness, permeability, good mechanical properties, and thermostability are challenging to obtain. Herein, robust and versatile composite microcapsules were fabricated using SiO 2 nanoparticle-stabilized (Pickering) oil emulsions as core templates, while silk fibroin (SF) was assembled at the oil/ water interface. This process resulted in the formation of physically and chemically stable microcapsules with a thick (∼800 nm) shell that protected the encapsulated ingredient from high shear forces and high temperatures during spray-drying. SiO 2 nanoparticles were randomly distributed in the shell matrix after preparation, making the microcapsules mechanically robust (4.48 times higher than control samples prepared using surfactant Tween 80 instead of the SiO 2 nanoparticles), as well as thermostable (retained shape to 900 °C). The microcapsules displayed tunable drug release by adjusting the SF content in the shell. Under optimal conditions (weight ratio of SiO 2 /SF = 7:10, corn oil content about 55 wt %), a model drug (curcumin) was encapsulated in the SF microcapsules with an encapsulation efficiency up to 95%. The in vitro drug release from these SF microcapsules lasted longer than control microcapsules, demonstrating the capability of these novel microcapsules in sustaining drug release.
Knitted fleece fabrics with superior comfort characteristics are chiefly focused in winter wear. Thermal characteristics are an area of interest in selecting fleece clothing. However, environmental hazards also need to be focused. Fleece clothing is worn in cold areas having higher ultraviolet rays exposures. Hence the clothing should have the capability of combating environmental challenges. The study focuses on engineering variable fleece structures with different materials. Cotton, nylon, and polypropylene fleece patterns have been knitted using fleece 1:1, 3:1, and 2:2 patterns. The designs vary by tuck and miss stitch configurations in the fleece course. Comfort characteristics were determined through air permeability, moisture management, and thermal resistance tests. Performance criteria were evaluated in terms of pilling resistance and ultraviolet protection factor (UPF) investigation. Structures and materials owing better comfort characteristics with satisfactory UPF have been predicted as safe clothing in UV affected zones, that is, fleece 3:1 possessed the optimum comfort characteristics and UPF simultaneously; however, the mechanical performance was better for 2:1 and 1:1 fleece fabric due to less amount of miss stitch floating yarns.
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