Achieving energy conservation and emission reduction in the industry is an inevitable way to promote harmony between society and nature and achieve sustainable human development. China’s infrastructure construction industry is developing rapidly. Still, there is a lack of a well-established industry standard for evaluating the potential and level of energy reduction in infrastructure construction. A severe lack of quantitative research on energy-saving and CO2 outflow decreases the benefits of green development advances. This study takes the energy conservation and outflow decrease of construction waste slurry treatment in Guangdong Province, China, as the background, establishes an evaluation system with three rule levels: social, economic, and environmental, and adopts rough set theory to determine the weights of each index to ensure the objectivity of each index. According to the recommendations of the carbon emission calculation guidelines, select the relevant data to evaluate the energy-saving and emission reduction benefits of the new green construction technology of grouted piles in a road project in Guangdong Province. The results show that the development level and potential of energy saving and emission reduction technology in the construction sector in Guangdong Province are increasing year by year. It’s potential changes with the increase or decrease of highway mileage, and it is an urgent need to increase investment in pollution control. The research results can evaluate the benefits of energy-saving and carbon dioxide emission reduction in the construction industry, also be used as a reference to assess energy-saving and emission reduction in the construction industry in other countries.
In this work, the high yield of MWNTs was prepared by chemical vapor deposition (CVD) method, followed by annealing at 2000–2800 °C, and the effects of high annealing temperature on metal impurities and defects in multi-walled carbon nanotubes (MWNTs) was explored. Furthermore, the annealed MWNTs were dispersed using a sand mill to make a conductive slurry, and finally the cathode LiNi0.5Co0.2Mn0.3O2 was added to the assembled batteries, and the application of MWNTs (slurry) as conductive agents in LiNi0.5Co0.2Mn0.3O2 (NCM) cathode materials by sand-mill dispersion on the performance of lithium-ion batteries was investigated. The results indicate that high temperature annealing can effectively remove the residual metal impurities from MWNTs and the defects in MWNTs gradually decreases as the temperature rises. In addition, 2 wt% of MWNTs (slurry) in LiNi0.5Co0.2Mn0.3O2 is sufficient to form an electronically conductive network; as a result, the electronic conductivity and the high rates performance of the LiNi0.5Co0.2Mn0.3O2 batteries were greatly improved. The LiNi0.5Co0.2Mn0.3O2 battery with MWNTs slurries annealed at 2200 ℃ as a conductive additive displays the highest initial discharge capacity of 173.16 mAh·g−1 at 0.1 C. In addition, after 100 cycles, a capacity retention of 95.8% at 0.5 C and a discharge capacity of 121.75 mAh·g−1 at 5 C were observed. The multi-walled carbon nanotubes used as conductive agents in LiNi0.5Co0.2Mn0.3O2 (NCM) cathode materials show excellent battery behaviors, which would provide a new insight for the development of high-performance novel conductive agents in lithium-ion batteries.
Nitrogen-doped carbon nanotubes (NCNTs) are obtained using a post-treatment method under different sintering temperatures. The catalysts can be removed from the Carbon Nanotubes (CNTs) within an acid treatment process. Then, the purified CNTs can be employed as a nitrogen doping basis. This research adds melamine as a nitrogen source during the sintering procedure under different temperatures to achieve NCNTs, which are applied to the cathodes. LiMn2O4 (LMO) cathode slurries are prepared using pristine CNTs and NCNTs samples as conductive additives. Coin cell lithium-ion batteries (LIBs) are fabricated using slurry samples. X-ray photoelectron spectroscopical analysis shows the nitrogen doping degree is up to 5 atom%, and graphitic-N nitrogen groups are the dominating species present on the NCNT’s surface while being treated at 800 °C. Graphitic-N nitrogen groups improve the conductivity and surface area of the NCNTs, which increases the rate capacity (106.8 mA h g−1 at 5 C) and cyclic retention (92.45% of initial capacity after 200 cycles at 5 C) of the lithium-ion batteries. The morphology of the NCNTs, the concentration of NCNTs elements, and the electrochemical performances of coin cell batteries are extensively discussed.
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