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Lip make-up products can be easily taken into body with food. For this reason, those products are requires to meet lots of qualifications compared with other cosmetic products. In addition, concerns about safety on synthesized tar pigments is constantly issued. Thus, demand of natural pigments is gradually increased and many kinds of natural pigments have been developed. However, there are some problems when natural pigments are applied to cometic products instead of synthetic ones. There is a reason that most of natural pigments consist of hydrophilic materials of sort of anthocyanin, but the existing lip make-up products is anhydrous oil dispersion type without water consisting oil and wax. Therefore, when watersoluble natural pigments are applied to anhydrous lip make-up products, color expression is lower and phase separation occurs due to the instability of the product. In addition, natural pigments have disadvantages that they can easily change by pH, heat and sunlight. There are troubles of stability because it is not easy to adjust for these factors in case of anhydrous forms. Aim of study is to develop lip make-up products which have not only safe to human but being high in expression of color by using natural pigments and securing stability of colorant as natural pigments are offered to polyol in oil emulsion. Then, lip make-up products which have heavy 1) † 주 저자 이동원⋅김영호⋅정은지⋅이상길⋅표형배 대한화장품학회지, 제 39권 제 1 호, 2013 moisture while having not dryness that is created when the moisture evaporates are developed.

Once powder base makeup products are applied to the skin, the products are formed a film and attached on the skin for 8 to 12 hours. The makeup film is deformed by secretions such as sweat and sebum secreted from the skin. Thus, durability of the film is an important quality factor in the makeup and its evaluation is also important. In this study, characteristics of the semi-finished powder products such as water absorption, oil absorption, water repellent and oil repellent were evaluated in a number of ways. Also, simple methods, which are not affected by evaluation conditions such as a difference between sweat and sebum secretion, temperature and humidity, were examined to predict the durability of the products. We measured water absorption, oil absorption, water repellent and oil-repellent properties of semifinished product by tablet, capillary and dipping method and then compared with the data of color difference meter and ROBO skin analyzer. Results showed that the durability of powder base makeup products was associated with more oil absorption and water-repellent characteristics than water absorption and oil-repellent. Oil absorption characteristics by tablet and capillary method and water-repellent characteristics by dipping method provides a simple and quick method to precdict the durability of the makeup products.

Amino group-terminated poly(N-isopropylacrylamide) (PNIPAAm-NH 2 ) was synthesized via a radical polymerization of N-isopropylacrylamide (NIPAAm) using 2-aminoethanethiol hydrochloride (AESH) as a chain transfer agent. The molecular weight of the PNIPAAm-NH 2 was controlled by changing the concentration of AESH. The LCST of the aqueous solution of PNIPAAm-NH 2 increased slightly with increasing the AESH concentration. Alginate-gPNIPAAm copolymer was synthesized by grafting PNIPAAm-NH 2 onto sodium alginate using N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide and N-hydroxysuccinimide. The formation of the grafted copolymers was confirmed by FTIR spectroscopy, solubility in water, and SEM-EDS. Alginate-g-PNIPAAm also exhibited swelling-deswelling behavior. However, it showed a LCST at a slightly increased temperature compared to PNIPAAm. The swelling ratio of the alginate-g-PNIPAAm hydrogel increased with the increase of the grafted PNIPAAm content.Keywords: poly(N-isopropylacrylamide), sodium alginate, graft, thermo-responsive property, swelling. 서 론

The transportation sector accounts for 33% of the total CO2 emissions. Effective control measures for reducing CO2 emissions are urgently needed to address global warming. Objective and reliable methods to estimate CO2 emissions are a prerequisite for the implementation of such effective control measures. However, existing models have not been successful. Even though the average-speed model is one of the most convenient and useful methods for estimating CO2 emissions, it cannot distinguish between a variety of roads as well as traffic conditions in the model. The results of this study found that there may be significant discrepancies between emissions estimated by the current average-speed model and those measured in real driving conditions. This paper proposed the subdivision of emission factors in the average-speed model depending on both traffic and road conditions.