On 22 June 2017, an extreme warm-sector rainfall event hit the western coastal area of South China, with maximum hourly and 12-h rainfall accumulations of 189.4 and 464.8 mm, respectively, which broke local historical records. Multisource observations were used to reveal multiscale processes contributing to the extreme rainfall. The results showed that a marine boundary layer jet (BLJ) coupled with a synoptic low-level jet (LLJ) inland played an important role in the formation of an extremely humid environment with a very low lifting condensation level of near-surface air. Under the favorable pre-convective conditions, convection was initialized at a mesoscale convergence line, aided by topographic lifting in the evening. During the nocturnal hours, the rainstorm developed and was maintained by a quasi-stationary mesoscale outflow boundary, which continuously lifted warm, moist air transported by the enhanced BLJ. When producing the extreme rainfall rates, the storm possessed relatively weak convection, with the 40 dBZ echo top hardly reaching 6 km. The extreme rainfall was produced mainly by the warm rain microphysical processes, mainly because the humid environment and the deep warm cloud layer facilitated the clouds’ condensational growth and collision–coalescence, and also reduced rain evaporation. As the storm evolved, the raindrop concentration increased rapidly from its initial stage and remained high until its weakening stage, but the mean raindrop size changed little. The extreme rain was characterized by the highest concentration of raindrops during the storm’s lifetime with a mean size of raindrops slightly larger than the maritime regime.