Water is the most widely used fire extinguishing agent. It is used to eliminate a wide range of fires, often occurring in ecologically sensitive areas. There is little information on the toxicity of the fire-fighting substances in connection with aquatic and terrestrial organisms. Toxic substances often present in fire waters slow down life processes. As a result, some organisms die. This study deals with the extinguishing of burning solids (fiberboard, cannabis, straw, cork) with extinguishing water and assessment of its effects on the aquatic and terrestrial environment. The following test organisms were selected to test the effects of the extinguishing water: Daphnia magna – consumer; and Sinapis alba and Lemna minor – producers. A preliminary test was carried out on all the samples to evaluate the (positive / negative) effects of the fire water on the test organisms. Specific conductivity, pH, and chemical oxygen demand were also determined. The results of this study call attention to negative impacts of extinguishing water on the environment. It is necessary to pay attention to prevention and thus eliminate potential risks. If environmental contamination can no longer be prevented, the spread of contaminated water must at least be reduced.