“…Electron field emitters (EFEs) play significant roles in micro/nanovacuum devices and optoelectronic applications such as field emission displays (FPD), vacuum amplifiers, field emission X-ray sources, and electron microtips. − Besides the great potential of EFEs in these applications, the utilization of high EFEs as cathode in microplasma (MP) devices has been demonstrated to be critical in enhancing the performance of the devices. , Generally, the MP devices are useful in many remarkable applications such as ozone production, display panels, and several bioelectronics and biomedical applications. − Several cold cathode materials, which perform very well in emission of electrons, were developed for these applications such as Mo, ZnO, Si, and CNTs. ,− However, these EFE materials mostly suffer from stability issues, − as cathode materials in a MP device are subjected to continuous plasma ion bombardment. Researchers are keen to develop a new generation of materials for MP devices that can overcome the deficiencies of existing the cathode materials. − Diamond-based materials have been attractive in the pursuit of good cathode materials for MP device applications due to their unique combination of superior EFE performance and MP-related characteristics, because diamond possesses negative electron affinity (NEA), superb electron field emission properties, large secondary electron emission behavior (large γ-coefficient), and high bonding strength (robustness). − …”