Ab initio electron scattering calculations using the R-matrix approach have been performed for N + 2 within a three-state valence configuration-interaction model (VCI). The lowest three electronic target states (X 2 + u , A 2 u and the B 2 + u ) of this molecular nitrogen cation are included in the close-coupling method, with each state being represented by a valence CI approximation. From a detailed analysis of the resonance structure found in our work for the 1,3 + g symmetries we find four prominent Rydberg series of the type npπ u , nfπ u , npσ u , nfσ u and a 2pσ u interloper resonance. This 2pσ u interloper molecular resonance associated with the B state of N + 2 is seen to cause distortions of the resulting resonance spectra. A comparison of our total cross sections for the X-B transition shows excellent agreement with the available experimental data. † Permanent address: