Biosensor Based on Screen-Printed Electrode and Glucose-Oxidase Modified with the Addition of Single-Walled Carbon Nanotubes and Thermoexpanded Graphite

Arlyapov, V. A.; Kamanin, S. S.; Kamanina, Olga A.; Reshetilov, A. N.

doi:10.1134/s1995078017060039

Cited by 8 publications

(3 citation statements)

References 31 publications

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“… 113 In, 122 MWCNTs modified with amino groups were applied when immobilizing GOx by cross-linking with glutaraldehyde; it resulted in a wider linear range of glucose determination and a higher biosensor sensitivity. In, 123 the biosensor based on GOx and polyaniline-modified MWCNTs was proposed; in ref. 124 GOx, SWCNTs and thermally expanded graphite were used.…”

Section: Use Of Organic Nanomaterials In Enzyme-based Biosensorsmentioning

confidence: 99%

Advances in nanomaterial application in enzyme-based electrochemical biosensors: a review

et al. 2019

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Electrochemical enzyme-based biosensors are one of the largest and commercially successful groups of biosensors. Integration of nanomaterials in the biosensors results in significant improvement of biosensor sensitivity, limit of detection, stability, response rate and other analytical characteristics. Thus, new functional nanomaterials are key components of numerous biosensors. However, due to the great variety of available nanomaterials, they should be carefully selected according to the desired effects. The present review covers the recent applications of various types of nanomaterials in electrochemical enzyme-based biosensors for the detection of small biomolecules, environmental pollutants, food contaminants, and clinical biomarkers. Benefits and limitations of using nanomaterials for analytical purposes are discussed. Furthermore, we highlight specific properties of different nanomaterials, which are relevant to electrochemical biosensors. The review is structured according to the types of nanomaterials. We describe the application of inorganic nanomaterials, such as gold nanoparticles (AuNPs), platinum nanoparticles (PtNPs), silver nanoparticles (AgNPs), and palladium nanoparticles (PdNPs), zeolites, inorganic quantum dots, and organic nanomaterials, such as single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNTs), carbon and graphene quantum dots, graphene, fullerenes, and calixarenes. Usage of composite nanomaterials is also presented. ). S. Dzyadevych is also working as a deputy director of the same institute since 2019. They received PhD degrees in biotechnology. They are developing electrochemical enzyme-based biosensors for medical, research, and industrial applications. The biosensors are based on amperometric, ISFET, and conductometric transducers and immobilized enzymes.a AgNPssilver nanoparticles; AuNPsgold nanoparticles; CNTscarbon nanotubes; NADHreduced nicotinamide adenine dinucleotide; PdNPs palladium nanoparticles; PtNPsplatinum nanoparticles; QDsquantum dots.This journal is Fig. 1 Ways of embedding NMs in the enzyme-based biosensors. (a) Enzyme immobilization on the NM-modified electrode. (b) Schematic of the biosensor based on phosphotriesterase (PTE) immobilized via glutaraldehyde on the graphene surface with platinum nanoparticles. Reprinted with permission from . 25 (c) Enzyme/NM co-immobilization on the electrode. (d) Schematic of the biosensor based on glucose oxidase encapsulated in a chitosan-kappa-carrageenan bionanocomposite. Reprinted from Material Science and Engineering: C, 95, I. Rassas, M. Braiek, A. Bonhomme, F. Bessueille, G. Rafin, H. Majdoub, and N. Jaffrezic-Renault, Voltammetric glucose biosensor based on glucose oxidase encapsulation in a chitosan-kappa-carrageenan polyelectrolyte complex, 152-159, Copyright (2018), with permission from Elsevier. 26 4562 | Nanoscale Adv., 2019, 1, 4560-4577 This journal is Fig. 5 Schematics of the hydrogen peroxide biosensor based on oligoaniline-cross-linked HRP/CNT composite and cyclic voltammograms of the bio...

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Section: Use Of Organic Nanomaterials In Enzyme-based Biosensorsmentioning

confidence: 99%

Advances in nanomaterial application in enzyme-based electrochemical biosensors: a review

et al. 2019

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“…Composites with carbon nanostructures are usually used to create electroactive polymers [ 110 , 111 , 112 ], which, in turn, could be used to create electrochemical sensors, such as glucose [ 113 , 114 , 115 , 116 ], as well as whole-cell sensors [ 117 , 118 , 119 ], which make it possible to evaluate such important integral parameters as biochemical oxygen demand based on individual strains [ 120 , 121 , 122 ] or activated sludge [ 123 , 124 ] or assessment of toxic effects [ 125 ]. Such systems can be used, for example, to monitor the fermentation process [ 126 ] or toxicant removement [ 127 ].…”

Section: Tuning the Properties Of Composites Through The Introduction...mentioning

confidence: 99%

On the Use of Polymer-Based Composites for the Creation of Optical Sensors: A Review

2022

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Polymers are widely used in many areas, but often their individual properties are not sufficient for use in certain applications. One of the solutions is the creation of polymer-based composites and nanocomposites. In such materials, in order to improve their properties, nanoscale particles (at least in one dimension) are dispersed in the polymer matrix. These properties include increased mechanical strength and durability, the ability to create a developed inner surface, adjustable thermal and electrical conductivity, and many others. The materials created can have a wide range of applications, such as biomimetic materials and technologies, smart materials, renewable energy sources, packaging, etc. This article reviews the usage of composites as a matrix for the optical sensors and biosensors. It highlights several methods that have been used to enhance performance and properties by optimizing the filler. It shows the main methods of combining indicator dyes with the material of the sensor matrix. Furthermore, the role of co-fillers or a hybrid filler in a polymer composite system is discussed, revealing the great potential and prospect of such matrixes in the field of fine properties tuning for advanced applications.

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“…Due to unique physical and chemical properties of FCNT electrochemical biosensors could be improved to give rise to amperometric enzyme electrodes, immunosensors and nucleic acid sensors (Desimone et al 2009). In this research we describe the feasibility of creation of a biosensor based on glucose oxidase enzyme and singlewalled carbon nanotubes for sensing glucose in alcoholic products (Arlyapov et al 2017).…”

Section: Introductionmentioning

confidence: 99%

Glucose biosensor based on screen-printed electrode modified with silicone sol–gel conducting matrix containing carbon nanotubes

et al. 2019

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This research shows that high-performance biosensors can be produced by modification of screen-printed electrodes with enzymes and conducting hydrogel based on sol-gel matrix and single-walled carbon nanotubes. Tetraethoxysilane, dimethyldiethoxysilane and polyvinyl alcohol were used as the sol-gel matrix basis. Modified SWCNT provide direct electron transfer during glucose oxidation, as confirmed by cyclic voltammetry. The developed conducting sol-gel screen-printed electrodes can determine glucose within the concentration range 0.045-1.04 mM. The developed biosensor is not only in pace with its world analogues but even exceeds them by some analytical and metrological properties. The developed conducting sol-gel biosensor was used to measure the concentration of glucose in blood. The test results differed only insignificantly from those received with the help of standard glucose meter.

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Biosensor Based on Screen-Printed Electrode and Glucose-Oxidase Modified with the Addition of Single-Walled Carbon Nanotubes and Thermoexpanded Graphite

Cited by 8 publications

References 31 publications

Advances in nanomaterial application in enzyme-based electrochemical biosensors: a review

Advances in nanomaterial application in enzyme-based electrochemical biosensors: a review

On the Use of Polymer-Based Composites for the Creation of Optical Sensors: A Review

Glucose biosensor based on screen-printed electrode modified with silicone sol–gel conducting matrix containing carbon nanotubes

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