Abstract:The electronic properties of the carbon substituted MgB2 single crystals are reported. The carbon substitution drops Tc below 2 K. In-plane resistivity shows a remarkable increase in residual resistivity by C-substitution, while the change of in-plane/out-of-plane Hall coefficients is rather small. Raman scattering spectra indicate that the E2g-phonon frequency radically hardens with increasing the carbon-content, suggesting the weakening of electron-phonon coupling. Another striking C-effect is the increases … Show more
“…The fact that there is no correlation of H c2 (0) with ρ across numerous samples leads to the suggestion that the measured resistivity is ρ π , while H c2 (0) is determined by σ-band scattering 15 (ρ σ ), with the magnitude of ρ σ being 125 to 165 µΩ cm. 6 However, to explain the observed form of H c2 (T), 16 and of irradiation, 14 and alloying with carbon, 4 is similar to that seen in many A15 and ternary boride superconductors, 17 it is not necessary to invoke interband scattering to explain such a reduction in T c . Smearing of the peak, and reduction of the density of states at the …”
Section: -10mentioning
confidence: 99%
“…Of particular interest is the large increase in H c2 that results from alloying with carbon, [1][2][3][4] and also, in the case of thin films, from disorder and possibly impurities that are introduced during deposition. 5 It has been shown that in Three MgB 2 thin films (A, S, and PB), all grown on sapphire substrates, were used for this study, while PA was used earlier.…”
a) J. Kim, a) B. Wilkens, b) N. Newman, a),b),g) J.M. Rowell, a) A.V. Pogrebnyakov, c),d),e) X.X. Xi, c),d),e) J.M. Redwing, d),e) S.Y. Xu, c),e) Qi Li, c),e) and B.H. Moeckly f)
“…The fact that there is no correlation of H c2 (0) with ρ across numerous samples leads to the suggestion that the measured resistivity is ρ π , while H c2 (0) is determined by σ-band scattering 15 (ρ σ ), with the magnitude of ρ σ being 125 to 165 µΩ cm. 6 However, to explain the observed form of H c2 (T), 16 and of irradiation, 14 and alloying with carbon, 4 is similar to that seen in many A15 and ternary boride superconductors, 17 it is not necessary to invoke interband scattering to explain such a reduction in T c . Smearing of the peak, and reduction of the density of states at the …”
Section: -10mentioning
confidence: 99%
“…Of particular interest is the large increase in H c2 that results from alloying with carbon, [1][2][3][4] and also, in the case of thin films, from disorder and possibly impurities that are introduced during deposition. 5 It has been shown that in Three MgB 2 thin films (A, S, and PB), all grown on sapphire substrates, were used for this study, while PA was used earlier.…”
a) J. Kim, a) B. Wilkens, b) N. Newman, a),b),g) J.M. Rowell, a) A.V. Pogrebnyakov, c),d),e) X.X. Xi, c),d),e) J.M. Redwing, d),e) S.Y. Xu, c),e) Qi Li, c),e) and B.H. Moeckly f)
“…A reduction of γ was reported after neutron irradiation [23,24] or can be achieved by carbon doping [30], but it seems to be always accompanied by an increase of the upper critical field B c2 (which further enhances B ⊥ c2 and enlarges the application range). Although experimentally difficult, the influence of such a "pure" change of anisotropy on J c is demonstrated in Fig.…”
The intrinsic properties of MgB2 form the basis for all applications of this superconductor. We wish to emphasize that the application range of polycrystalline MgB2 is limited by the upper critical field Hc2 and its anisotropy. In wires or tapes, the MgB2 grains are randomly oriented or only slightly textured and the anisotropy of the upper critical field leads to different transport properties in different grains, if a magnetic field is applied and the current transport becomes percolative. The irreversibility line is caused by the disappearance of a continuous superconducting current path and not by depinning as in high temperature superconductors. Based on a percolation model, we demonstrate how changes of the upper critical field and its anisotropy and how changes of flux pinning will influence the critical currents of a wire or a tape. These predictions are compared to results of neutron irradiation experiments, where these parameters were changed systematically.
“…Reduction of coherence length due to enhanced impurity scattering is considered to contribute to the enhancement of H c2 [30][31][32][33] . Furthermore, flux pinning strength was found to be enhanced by carbon substitution 6,19,20,23,24 .…”
We report the synthesis and characterization of graphite (C) doped MgB 2-x C x (x = 0.0, 0.1, 0.2 and 0.3) samples. The crystal structure and microstructural characterization have been investigated by x-ray diffractometer and transmission electron microscopic (TEM) analysis. The superconducting properties especially J c and H c2 have been measured by employing physical property measurement system. We found that the graphite doping affects the lattice parameters as well as the microstructure of MgB 2 superconductor. In case of optimally doped (x = 0.1) sample, the critical current density at 5K corresponds to 1.1 x 10 6 and 5.3 x 10 4 A/cm 2 for 3T and 5T fields respectively. The upper critical field has been enhanced nearly two times after doping. The flux pinning behavior has been investigated by flux pinning force density curve and it reveals that the flux pinning behaviour has improved significantly by doping. TEM micrographs show the graphite nanoparticles of size ~5-10 nm which are invariably present in MgB 2 grains. These nanoparticles act as flux pinning centre and are responsible for enhancement of superconducting properties of MgB 2 .
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