The
production of flexible monocrystalline semiconductor thin films
less than a few tens of micrometers in thickness is currently receiving
huge interest in various emerging applications such as mobile health
care (mHealth), wearable devices, smart cities, and Internet of things
(IoT). However, conventional techniques fail to produce wafer-scale
monocrystalline thin films without the use of sophisticated equipment.
Recently, the controlled cracking method has shown promise as a facile
and scalable method to produce monocrystalline inorganic semiconductor
thin films such as Si, Ge, III–V, and III–N materials.
In this method, a crystalline semiconductor thin film can be exfoliated
from its thick donor substrate via subsurface crack propagation. The
cracking based layer transfer approach does not require expensive
processing equipment and enables the production of multiple thin films
from the same donor substrate. In this review, we present the working
principles, recent progress, and future prospects of this emerging
crack-assisted layer transfer technology. The unique advantages of
this technology for state-of-the-art flexible (opto)electronics are
also highlighted. This review offers insights for the fabrication
of large-scale flexible monocrystalline semiconductors, which is crucial
for the development of next-generation (opto)electronics.