The frequency-dependent capacitance
of low-temperature solution-processed
metal oxide (MO) dielectrics typically yields unreliable and unstable
thin-film transistor (TFT) performance metrics, which hinders the
development of next-generation roll-to-roll MO electronics and obscures
intercomparisons between processing methodologies. Here, capacitance
values stable over a wide frequency range are achieved in low-temperature
combustion-synthesized aluminum oxide (AlO
x
) dielectric films by fluoride doping. For an optimal F incorporation
of ∼3.7 atomic % F, the F:AlO
x
film
capacitance of 166 ± 11 nF/cm2 is stable over a 10–1–104 Hz frequency range, far more
stable than that of neat AlO
x
films (capacitance
= 336 ± 201 nF/cm2) which falls from 781 ± 85
nF/cm2 to 104 ± 4 nF/cm2 over this frequency
range. Importantly, both n-type/inorganic and p-type/organic TFTs
exhibit reliable electrical characteristics with minimum hysteresis
when employing the F:AlO
x
dielectric with
∼3.7 atomic % F. Systematic characterization of film microstructural/compositional
and electronic/dielectric properties by X-ray photoelectron spectroscopy,
time-of-fight secondary ion mass spectrometry, cross-section transmission
electron microscopy, solid-state nuclear magnetic resonance, and UV–vis
absorption spectroscopy reveal that fluoride doping generates AlOF,
which strongly reduces the mobile hydrogen content, suppressing polarization
mechanisms at low frequencies. Thus, this work provides a broadly
applicable anion doping strategy for the realization of high-performance
solution-processed metal oxide dielectrics for both organic and inorganic
electronics applications.