Constituents of Pyrethrum Flowers. XXIII. Cinerolone and the Synthesis of Related Cyclopentenolones

Schechter, M. S.; Green, Nathan; LaForge, F. B.

doi:10.1021/ja01177a065

Cited by 134 publications

(33 citation statements)

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“…Many early attempts at pyrethroid synthesis focused on substitutions to the alcohol portion of the molecule (6,7). Allethrin was one of the earliest synthetic analogues to eventually achieve commercial success, and allethrin-containing products are still marketed throughout the world today.…”

Section: First-generation Photolabile Synthetic Pyrethroidsmentioning

confidence: 99%

Synthetic Pyrethroid Use Patterns, Properties, and Environmental Effects

Spurlock

Marshall

2008

ACS Symposium Series

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Section: First-generation Photolabile Synthetic Pyrethroidsmentioning

confidence: 99%

Synthetic Pyrethroid Use Patterns, Properties, and Environmental Effects

Spurlock

Marshall

2008

ACS Symposium Series

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“…Chloride currents were also exposed to a pyrethroid of both the type 1 (allethrin) and type 2 (FNV) categories, respectively [11,12], and compared to control currents in DMSO (0.1%) to determine any significant effects on overall current amplitudes (Fig. 6).…”

Section: Resultsmentioning

confidence: 99%

Insecticide sensitivity of native chloride and sodium channels in a mosquito cell line

Jenson

Anderson

Bloomquist

2016

Pesticide Biochemistry and Physiology

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“…The first important synthetic compound, still used today, was allethrin, developed by Schechter, Green, and La Forge in 1949 (29), by shortening and simplifying the pentadienyl side chain of the natural esters (4,5). Allethrolone, the alcoholic component, is now resolved on a commercial scale, (7,35).…”

Section: Structure and Insecticidal Activitymentioning

confidence: 99%

Properties and applications of pyrethroids.

Elliott¹

1976

Environ Health Perspect

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Improved understanding of the factors determining the insecticidal activity, the mammalian toxicity, and the stability in air and light of natural and synthetic pyrethroids has led to a series of new compounds with a very favorable combination of properties. Their characteristicsinclude outstanding potency to insects, low toxicity to mammals associated with rapid metabolic breakdown and, in appropriate cases, adequate stability on plant surfaces even in bright sunlight. Initial tests indicate that even the more stable compounds are degraded rapidly in soil, so if the trials at present in progress reveal no toxicological or environmental hazards, within a few years synthetic pyrethroids should be available to control a wide range of domestic, veterinary, horticultural, agricultural, and forest pests at low rates of application.

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Constituents of Pyrethrum Flowers. XXIII. Cinerolone and the Synthesis of Related Cyclopentenolones

Cited by 134 publications

References 0 publications

Synthetic Pyrethroid Use Patterns, Properties, and Environmental Effects

Synthetic Pyrethroid Use Patterns, Properties, and Environmental Effects

Insecticide sensitivity of native chloride and sodium channels in a mosquito cell line

Properties and applications of pyrethroids.

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