When they were first conceived, solar cooling systems were designed to be cost-effective and environmentally safe alternatives for the majority of the developing nations that are characterised by their hot climates in contrast with the traditional air conditioning systems powered by electricity that is produced from fossil fuel resources. Nevertheless, developments in photovoltaic (PV) and air-conditioning technologies have impacted on the prospects of solar cooling systems. This study examined two different options: a coupled PV and air conditioner system and a solar cooling system (absorption chillers where thermal energy is provided by solar collectors) for a specific developing country located in the Eastern Mediterranean region whose climate is hot and dry (Jordan). The cooling system comprised a pair of cooled multistage compression, both of which were 700 kW, while the PV system’s size was 2.1 MWp, the utility grid connection was a 0.4 kV 50 Hz net meter (2 m) and it was anticipated that 3300 MWh/year would be generated. The solar cooling system operated at a maximum coefficient of performance (COP) of 0.79 and had an actual recorded COP of 0.32 on the site; when the electricity tariff of $0.1/kWh was considered, the respective levelised cost of energy (LCOE) values were $0.9/kWh and $2.35/kWh respectively. The findings indicate that the initial costs for the solar thermal cooling system and the PV system were approximately $3.150M and $3M, respectively. The current value of future cash payments when discounts of 6% per year were applied to the payments for the combination of PV and air conditioning was about $9,745,000, whereas the solar thermal cooling system will not reach the breakeven point at negative $1,730,000. It is clear the absorption chiller did not display economic feasibility, whereas the value for the coupled PV and air-conditioning systems was under $0.05/kWh. In addition to the extensive maintenance needs, the reduced COP and the practicality and feasibility of the solar thermal cooling systems mean these kinds of technologies are under significant pressure to remain competitive when faced with the development of new air conditioning and PV technologies.