In this study, hydrogen
peroxide (H2O2) cosolvent,
which was dissolved into supercritical-phase carbon dioxide fluid
(SCCO2), is employed to passivate excessive oxygen vacancies
of the high-mobility tungsten-doped indium oxide without any essential
thermal process. With the detailed material analysis, the internal
physical mechanism of the cosolvent effect or the interaction between
the cosolvent solution and supercritical-phase fluid is well discussed.
In addition, the optimized result has been applied for the thin film
transistor device fabrication. As a result, the device with SCCO2 + H2O2 treatment exhibits the lowest
subthreshold swing of 82 mV/dec, the lowest interface trap density
of 8.76 × 1011 eV–1 cm–2, the lowest hysteresis of 47 mV, and an excellent reliability and
uniformity characteristic compared with any other control groups.
Besides, an extremely high field-effect mobility of 98.91 cm2/V s can also be observed, while there is even a desirable positive
shift for the threshold voltage. Notably, compared with the untreated
sample, the highest on/off current ratio of 5.11 × 107 can be achieved with at least four orders of magnitude enhancement
by this unique treatment.