This work revealed the basic mechanism for the stabilization of carbon in ultra-low-carbon (ULC) steels that contain moderate S (0.004 to 0.010 wt pct), adequate Ti (0.060 to 0.080), and low Mn (≤0.20). During cooling through the austenitic region to the ferritic, the initially formed sulfide particles (TiS) undergo an in situ transformation into carbosulfides (H-Ti 4 C 2 S 2 ) by absorbing C and Ti. The transformation from TiS to H may be considered as a hybrid of shear and diffusion, i.e., faulted Ti 8 S 9 (9R) ϩ 10[Ti] ϩ 9[C] → 4 1 /2Ti 4 C 2 S 2 (H). At low temperature (≤930 ЊC), the stabilization process continues through epitaxial growth of carbides on H phase, i.e., [M] . This mechanism differs from the traditional view of stabilization, where the carbon is removed from solution by the formation of free-standing or independently nucleated H and/or MCN precipitates. While these two forms of carbon stabilization are now well known, this article presents a method of predicting which mechanism of stabilization will be operative in a given steel based on its bulk composition. Implications bearing upon new ULC steel design, considering the role of S, will be discussed.